Morpholine-4-carbodithioate;trimethylstannanylium | 35777-92-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: Morpholine-4-carbodithioate;trimethylstannanylium
• CAS: 35777-92-5
• 化学式: C₈H₁₇NOS₂Sn
• 分子量: 326.071
• InChiKey: BPWWYWORPYMYIC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.17
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  69.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  sodium N-morpholinocarbamodithioate 、 三甲基氯化锡 以 苯 为溶剂， 以90%的产率得到Morpholine-4-carbodithioate;trimethylstannanylium
  参考文献：
  名称：

  SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF HETEROCYCLIC DITHIOCARBAMATE COMPLEXES OF TRIORGANOTIN (IV)

  摘要：

  Heterocyclic dithiocarbamate complexes of triorganotin (IV) having general formula, CH(2)CH(2)XCH(2)NCS(2)SnR(3) (where X = >CH2, >CH-CH3, >N-CH3, >O; R = -CH3 and C6H5) have been synthesized by the reaction of triorganotin chloride with the sodium salt of the corresponding ligand in 1:1 stoichiometry. These complexes have been characterized by elemental analysis, molecular weight measurements, IR and NMR (H-1, C-13,d Sn-119) spectroscopy, suggesting that the methyl tin complexes are probably four coordinate, while the phenyl tin ones are probably five-coordinate with bidentate dithiocarbamate.

  DOI：

  10.1080/10426509608046344