1,5-bis(2,2-dimethyl-3-propanol-amino)antraquinone

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,5-bis(2,2-dimethyl-3-propanol-amino)antraquinone
• 英文别名: 1,5-bis[(3-hydroxy-2,2-dimethylpropyl)amino]anthraquinone；1,5-Bis[(3-hydroxy-2,2-dimethylpropyl)amino]anthracene-9,10-dione
• 化学式: C₂₄H₃₀N₂O₄
• 分子量: 410.513
• InChiKey: PEGWTYUTVJVAJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  30
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  98.7
• 氢给体数：
  4
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,5-bis(2,2-dimethyl-3-propanol-amino)antraquinone 在 溴 作用下， 以 溶剂黄146 、 丙酸 为溶剂， 生成 4-Bromo-1,5-bis-(3-hydroxy-2,2-dimethyl-propylamino)-anthraquinone 、 1,5-Dibromo-4,8-bis-(3-hydroxy-2,2-dimethyl-propylamino)-anthraquinone
  参考文献：
  名称：

  Acid-Aided Selectivity in Bromination of 1-Aminoanthraquinones

  摘要：

  Selectivity in the bromination of 1-aminoanthraquinones was studied. The addition of mineral acids was surprisingly found to enhance selectivity for the four isomer and consequently givean enhanced yield.

  DOI：

  10.1080/00397919508010785
• 作为产物：
  描述：

  3-氨基-2,2-二甲基-1-丙醇 、 1,5-二氯蒽醌 以 乙二醇乙醚 、 水 为溶剂， 以82%的产率得到1,5-bis(2,2-dimethyl-3-propanol-amino)antraquinone
  参考文献：
  名称：

  Copolymerized anthraquinone-polyester color concentrates

  摘要：

  本文揭示了一种颜色浓缩物组合物，其包括聚酯，其中至少有0.5重量百分比的蒽醌色素化合物共聚其中，其具有以下结构式：其中AQ是1,5-或1,8-蒽醌基团；R.sup.1和R.sup.2相同或不同，为未取代或取代的烷基、环烷基或芳基；X是与制备聚酯的单体的功能团之一至少反应的基团。无定形聚酯和部分结晶聚酯是颜色浓缩物的首选实施形式。还揭示了可以通过溶解-结晶-沉淀程序从无定形和部分结晶颜色浓缩物获得的着色半结晶粉末。

  公开号：

  US05032670A1

文献信息

• Solid-form additive systems dispersible in aqueous media, methods for the preparation and application thereof to polymeric particles
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP0413647A2

  公开（公告）日：1991-02-20

  Melting meltable polymer additives, adding at least two surfactants, one with low HLB value and one with high HLB value under sufficient agitation and cooling the resulting homogeneous melt.

  熔化可熔聚合物添加剂，在充分搅拌下加入至少两种表面活性剂，一种是 HLB 值低的，另一种是 HLB 值高的，然后冷却得到的均匀熔体。
• Copolymerized anthraquinone-polyester colour concentrates
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP0417017A1

  公开（公告）日：1991-03-13

  Disclosed are color concentrate compositions which comprise a polyester having copolymerized therein at least 0.5 weight percent of an anthraquinone colorant compound having the formula wherein AQ is a 1,5- or 1,8-anthraquinonylene radical; R1 and R2 are the same or different and are unsubstituted or substituted alkyl, cycloalkyl or aryl; and X is a group reactive with at least one of the functional groups of the monomers from which the polyester is prepared. Amorphous polyesters and partially-crystalline polyesters are preferred embodiments of the color concentrates. Also disclosed are colored semicrystalline powders which may be obtained from the amorphous and partially-crystalline color concentrates by a dissolution-crystallization-precipitation procedure.

  所公开的色素浓缩物组合物包含一种聚酯，其中共聚有至少 0.5 重量百分比的蒽醌着色剂化合物，其式如下 其中 AQ 是 1,5- 或 1,8- 蒽醌基；R1 和 R2 相同或不同，是未取代或取代的烷基、环烷基或芳基；X 是与制备聚酯的单体中至少一个官能团反应的基团。无定形聚酯和部分结晶聚酯是彩色浓缩物的优选实施方案。此外，还公开了彩色半结晶粉末，可通过溶解-结晶-沉淀程序从无定形和部分结晶彩色浓缩物中获得。
• Thermally stable, anthraquinone colorants containing copolymerizable vinyl groups
  申请人：——

  公开号：US20020068725A1

  公开（公告）日：2002-06-06

  Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as acrylate and methacrylate polymeric materials. The compounds possess good fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are (1) coating composition comprising (i) one or more polymerizable vinyl compounds, (ii) one or more of the dye compounds described above, and (iii) a photoinitiator and (2) polymeric materials, i.e., polymers derived from one or more acrylic acid esters, one or more methacrylic acid esters, one or more other polymerizable vinyl compounds or mixtures of any two or more thereof, having copolymerized therein one or more of the anthraquinone colorant compounds.

  本发明公开了热稳定性蒽醌着色剂化合物（染料），该化合物含有一个或多个乙烯基，可与反应性乙烯基单体共聚，从而生产出有色的聚合物组合物，如丙烯酸酯和甲基丙烯酸酯聚合物材料。这些化合物具有良好的紫外线（UV）牢度（稳定性）、在乙烯基单体中的良好溶解性、良好的着色力和出色的热稳定性。还公开了（1）涂料组合物，包括（i）一种或多种可聚合乙烯基化合物；（ii）一种或多种上述染料化合物；（iii）光引发剂；（2）聚合物材料，即由一种或多种丙烯酸酯、一种或多种甲基丙烯酸酯、一种或多种其他可聚合乙烯基化合物或其中任意两种或多种的混合物衍生的聚合物，其中共聚有一种或多种蒽醌着色剂化合物。
• [EN] COLORED, RADIATION-CURABLE COMPOSITIONS<br/>[FR] COMPOSITIONS DE COULEUR, DURCISSABLES PAR RAYONNEMENTS
  申请人：CIT ALCATEL

  公开号：WO2002098945A1

  公开（公告）日：2002-12-12

  Radiation-curable compositions, and methods of making the same, for providing a wide variety of substrates with a durable, colored coating or colorant are disclosed. The color is at least in part provided by chromophore molecules that are covalently bonded to other components within the radiation-curable composition. A telecommunication element having a durable color identifying polymeric coating thereon is also disclosed. The telecommunication element comprises an elongated communication transmission medium, such as an optical fiber or an optical fiber ribbon, and a radiation-cured polymeric coating having an identifying color applied on at least a portion of the transmission medium.

  本发明公开了一种辐射固化组合物及其制备方法，用于为各种基材提供耐用的彩色涂覆层或着色剂。所述颜色至少部分由共价键合在辐射固化组合物的其他组分中的色基（chromophore）分子提供。此外，本发明还公开了一种带有耐用颜色识别聚合物涂覆层的通信元件。所述通信元件包括一种延长的通信传输介质，如光纤或光纤带，以及一种在传输介质的至少一部分上施加并具有识别颜色的辐射固化聚合物涂覆层。
• Polyesters colored with the residue of heat stable anthraquinone compounds
  申请人：EASTMAN CHEMICAL COMPANY

  公开号：EP0415859B1

  公开（公告）日：1993-11-03