2-(3-isopropenylphenyl)propan-1-ol | 457928-66-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(3-isopropenylphenyl)propan-1-ol
• 英文别名: 2-(3-Prop-1-en-2-ylphenyl)propan-1-ol
• CAS: 457928-66-4
• 化学式: C₁₂H₁₆O
• 分子量: 176.258
• InChiKey: NZTNUZHWPDDWRV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(3-isopropenylphenyl)propan-1-ol 在 palladium on activated charcoal 、 5% Pd on active carbon porcine pancreatic lipase 、 氢气 作用下， 以 乙酸乙酯 为溶剂， 反应 144.0h， 生成 alpha-甲基-3-异丙基苯乙醇
  参考文献：
  名称：

  Biocatalysed synthesis of the enantiomers of the floral odorant Florhydral®

  摘要：

  The two enantiomers of the floral odorant Florhydral(R) were prepared by enzymatic methods, and their olfactory properties were evaluated. (+)-Florhydral(R) was found to be Much more powerful than the (-)-enantionier. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00202-1
• 作为产物：
  描述：

  1,3-二异丙烯基苯 在 dimethyl sulfide borane 、 sodium hydroxide 、 双氧水 作用下， 以 四氢呋喃 为溶剂， 以55%的产率得到2-(3-isopropenylphenyl)propan-1-ol
  参考文献：
  名称：

  Biocatalysed synthesis of the enantiomers of the floral odorant Florhydral®

  摘要：

  The two enantiomers of the floral odorant Florhydral(R) were prepared by enzymatic methods, and their olfactory properties were evaluated. (+)-Florhydral(R) was found to be Much more powerful than the (-)-enantionier. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0957-4166(02)00202-1

文献信息

• PROCESS FOR THE PREPARATION OF A THERMOPLASTIC ELASTOMERIC VULCANIZATE
  申请人：Stichting Dutch Polymer Institute

  公开号：EP1694765A2

  公开（公告）日：2006-08-30
• [EN] PROCESS FOR THE PREPARATION OF A THERMOPLASTIC ELASTOMERIC VULCANIZATE<br/>[FR] PROCESSUS DE PREPARATION D'UN VULCANISAT ELASTOMERE THERMOPLASTIQUE
  申请人：STICHTING DUTCH POLYMER INST

  公开号：WO2005054360A2

  公开（公告）日：2005-06-16

  The invention deals with a process for the preparation of a thermoplastic elastomeric vulcanizate, based on a polyolefin and a rubber. The rubber is vulcanized with an organic peroxide having at least one terminal carbon-carbon bond in the molecule. As a result, blooming effects are reduced and physical properties are improved.
• Biocatalysed synthesis of the enantiomers of the floral odorant Florhydral®
  作者：Agnese Abate、Elisabetta Brenna、Claudia Dei Negri、Claudio Fuganti、Stefano Serra

  DOI：10.1016/s0957-4166(02)00202-1

  日期：2002.5

  The two enantiomers of the floral odorant Florhydral(R) were prepared by enzymatic methods, and their olfactory properties were evaluated. (+)-Florhydral(R) was found to be Much more powerful than the (-)-enantionier. (C) 2002 Elsevier Science Ltd. All rights reserved.