cobalt(II) maleate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: cobalt(II) maleate
• 英文别名: (Z)-but-2-enedioate;cobalt(2+)
• 化学式: C₄H₂O₄*Co
• 分子量: 173.051
• InChiKey: RKHIWEUVOCCWMO-ODZAUARKSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.96
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  cobalt(II) maleate 、 水 、 顺丁烯二酸 以 水 为溶剂， 生成 tetraaquabis(hydrogen maleato)cobalt(II)
  参考文献：
  名称：

  Transition-metal bimaleates and their solid solutions: Synthesis, structural, and thermoanalytical study

  摘要：

  Transition-metal hydrogen maleates of composition M(C4H3O4)(2) center dot 4H(2)O, where M = Mn, Fe, Co, and Ni, and their solid solutions were synthesized and characterized by X-ray crystallography, IR spectroscopy, mass spectrometry, and thermal analysis. X-ray crystallography and IR spectroscopy showed that both intramolecular and intermolecular H-bonds exist in these compounds. The generation of continuous substitutional solid solutions with cation substitution in these compounds was studied. The thermolysis mechanism was studied for both transition-metal hydrogen maleates and their solid solutions. The composite produced by thermolysis is stable up to 1200 degrees C in flowing helium.

  DOI：

  10.1134/s0036023608090180
• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 furan-2-ol 、 cobalt(II) maleate
  参考文献：
  名称：

  Fechtel, Guenter, Zeitschrift fur Chemie, 1989, vol. 29, # 1, p. 28

  摘要：

  DOI：