3-ethoxy-N,N-dimethylpropionic acid amide | 24475-97-6

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-ethoxy-N,N-dimethylpropionic acid amide
• 英文别名: 3-ethoxy-N,N-dimethylpropanamide
• CAS: 24475-97-6
• 化学式: C₇H₁₅NO₂
• 分子量: 145.202
• InChiKey: PVKDNXFNSSLPRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-ethoxy-N,N-dimethylpropionic acid amide 、 苯乙炔 生成 5-Ethoxy-1-phenyl-pent-1-yn-3-one
  参考文献：
  名称：

  Somin,I.N.; Germanguz,E.A., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, p. 1727 - 1730

  摘要：

  DOI：
• 作为产物：
  描述：

  二甲胺 、 3-ethoxypropionyl chloride 以 乙醚 为溶剂， 生成 3-ethoxy-N,N-dimethylpropionic acid amide
  参考文献：
  名称：

  Somin,I.N.; Germanguz,E.A., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, p. 1727 - 1730

  摘要：

  DOI：

文献信息

• METHOD FOR PRODUCING BETA -ALKOXYPROPIONAMIDE
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2837619A1

  公开（公告）日：2015-02-18

  A method for producing a β-alkoxypropionamide including reacting a β-alkoxypropionic acid ester represented by the following formula (1) and an amine represented by the following formula (2) in the presence of a polyol and a basic catalyst, thereby to produce a β-alkoxypropionamide represented by the following formula (3), wherein, as the polyol, a reaction residue that is generated by the reaction and contains a used polyol is used: (wherein in the formulas, R and R' are independently a C1 to C6 linear, branched or cyclic, saturated hydrocarbon group; R1 and R2 are independently a C1 to C6 linear, branched or cyclic, saturated hydrocarbon group; and R3 is H or CH3).

  生产β-烷氧基丙酰胺的方法包括在多元醇和碱性催化剂存在下，使以下式（1）所代表的β-烷氧基丙酸酯与以下式（2）所代表的胺发生反应，从而生成以下式（3）所代表的β-烷氧基丙酰胺， 其中作为多元醇，使用由反应生成并含有已使用的多元醇的反应残留物：（在公式中，R和R'分别是C1到C6的直链、支链或环状饱和碳氢基团；R1和R2分别是C1到C6的直链、支链或环状饱和碳氢基团；R3是H或CH3）。
• METHOD FOR PRODUCING BETA-ALKOXYPROPIONAMIDE
  申请人：Shiraki Yasushi

  公开号：US20110251430A1

  公开（公告）日：2011-10-13

  A method for producing a β-alkoxypropionamide including: subjecting a β-alkoxypropionic acid ester represented by the following formula (I) and a polyol having two or more OH groups to a transesterification reaction in the presence of a basic catalyst, thereby to synthesize a transesterified polyol of a β-alkoxypropionic acid ester; and subjecting the transesterified polyol and an amine represented by the following formula (II) to an amidation reaction, thereby to synthesize a β-alkoxypropionamide represented by the following formula (III):

  生产β-烷氧基丙酰胺的方法包括： 在存在碱性催化剂的情况下，将以下式(I)所代表的β-烷氧基丙酸酯和具有两个或更多羟基的多元醇进行酯交换反应，从而合成β-烷氧基丙酸酯的酯交换多元醇；以及 将酯交换多元醇和以下式(II)所代表的胺进行酰胺化反应，从而合成以下式(III)所代表的β-烷氧基丙酰胺。
• Pyrazole Compounds for Controlling Invertebrate Pests
  申请人：GROSS Steffen

  公开号：US20140068820A1

  公开（公告）日：2014-03-06

  The present invention relates to novel pyrazole compounds of the formulae I and II, to their salts and their N-oxides which can be used for combating or controlling invertebrate pests, in particular arthropod pests. The invention also relates to a method for controlling invertebrate pests by using these compounds. The present invention also relates to seed and to an agricultural and veterinary composition comprising said compounds. wherein A is a pyrazole radical of the formulae A1, A2 or A3 # denotes the binding site to the remainder of formulae I or II; X 1 is S, O or NR 1a ; X 2 is OR 2a , NR 2b R 2c , S(O) m R 2d ; X 3 is a lone pair or oxygen; R 1 , R 2 and R 3 are, inter alia, hydrogen, and wherein R 41 , R 42 , R 43 , R 51 , R 52 , R 53 , R 61 , R 62 , R 63 , are as defined in claim 1.

  本发明涉及式I和式II的新型吡唑化合物及其盐和N-氧化物，可用于对抗或控制无脊椎动物害虫，特别是节肢动物害虫。本发明还涉及使用这些化合物控制无脊椎动物害虫的方法。本发明还涉及种子以及包含该化合物的农业和兽医组合物。其中，A是式A1、A2或A3的吡唑基团；#表示与式I或II的其余部分的结合位点；X1是S、O或NR1a；X2是OR2a、NR2bR2c、S（O）mR2d；X3是孤对电子或氧；R1、R2和R3等等为氢；R41、R42、R43、R51、R52、R53、R61、R62和R63如权利要求1所定义。
• INK COMPOSITION, INK SET, AND IMAGE FORMING METHOD
  申请人：FUJIFILM CORPORATION

  公开号：US20150175819A1

  公开（公告）日：2015-06-25

  An ink composition, including: water; a polymerizable compound; a polymerization initiator; and a β-alkoxypropionamide compound represented by the following Formula (A): wherein, in Formula (A), R 1 represents a linear or branched alkyl group having from 1 to 6 carbon atoms; each of R 2 and R 3 independently represents a hydrogen atom or a linear or branched alkyl group having from 1 to 4 carbon atoms; and R 2 and R 3 may be the same or different.

  一种墨水组合物，包括：水；可聚合化合物；聚合引发剂；以及由以下式子（A）表示的β-烷氧基丙酰胺化合物：其中，在式（A）中，R1表示具有1至6个碳原子的线性或支链烷基；每个R2和R3独立地表示氢原子或具有1至4个碳原子的线性或支链烷基；且R2和R3可以相同也可以不同。
• PROCESS FOR PRODUCING -ALKOXYPROPIONAMIDE
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2123631A1

  公开（公告）日：2009-11-25

  A method for producing a β-alkoxypropionamide shown by the following formula (I) including the step of reacting a β-alkoxypropionic acid ester with an amine in the presence of a basic catalyst or in the presence of a basic catalyst and a polyol: wherein R1 is an alkyl group having 1 to 8 carbon atoms, and R2 and R3 are independently hydrogen, a methyl group, an ethyl group, a methoxy group, an ethoxy group, a methoxymethyl group or a glycidyl group.

  一种生产下式(I)所示β-烷氧基丙酰胺的方法，包括β-烷氧基丙酸酯在碱性催化剂存在下或在碱性催化剂和多元醇存在下与胺反应的步骤： 其中 R1 是具有 1 至 8 个碳原子的烷基，R2 和 R3 独立地是氢、甲基、乙基、甲氧基、乙氧基、甲氧基甲基或缩水甘油基。