1,6-bis(4-aminobenzoyloxy)hexane | 101156-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,6-bis(4-aminobenzoyloxy)hexane
• 英文别名: 6-[(4-aminobenzoyl)oxy]hexyl 4-aminobenzoate；6-(4-aminobenzoyl)oxyhexyl 4-aminobenzoate
• CAS: 101156-14-3
• 化学式: C₂₀H₂₄N₂O₄
• 分子量: 356.422
• InChiKey: QBDRXTGMDLVVRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  26
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  105
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,6-bis(4-aminobenzoyloxy)hexane 在 盐酸 、 sodium nitrite 作用下， 以 DMF (N,N-dimethyl-formamide) 、 水 为溶剂， 反应 0.75h， 生成
  参考文献：
  名称：

  Polymerizable dichromophoric dichroic azo dyes

  摘要：

  本发明涉及可聚合的双色性二色性偶氮染料，包括偶氮色团，其上附有可聚合基团，从而产生具有足够溶解性、高着色力和高序参数的染料。

  公开号：

  EP1593713A1
• 作为产物：
  描述：

  hexane-1,6-diyl bis(p-nitrobenzoate) 在 palladium 10% on activated carbon 氢气 作用下， 以 四氢呋喃 、 乙酸乙酯 为溶剂， 以97%的产率得到1,6-bis(4-aminobenzoyloxy)hexane
  参考文献：
  名称：

  Polymerizable dichromophoric dichroic azo dyes

  摘要：

  本发明涉及可聚合的双色性二色性偶氮染料，包括偶氮色团，其上附有可聚合基团，从而产生具有足够溶解性、高着色力和高序参数的染料。

  公开号：

  EP1593713A1

文献信息

• Polymerizable Dichromophoric Dichroic Azo Dyes
  申请人：Peglow Thomas

  公开号：US20080001120A1

  公开（公告）日：2008-01-03

  The present invention is directed towards polymerizable dichromophoric dichroic azo dyes comprising azo-chromophores to which polymerizable groups are attached leading to dyes having sufficient solubility in combination with high coloring power and high order parameter.

  本发明涉及可聚合的二色性偶氮染料，包括连接聚合基团的偶氮色团，从而得到具有足够溶解度、高着色力和高序参量的染料。
• Eingedickte Formmassen
  申请人：BASF Aktiengesellschaft

  公开号：EP0308745A2

  公开（公告）日：1989-03-29

  Die Erfindung betrifft eine eingedickte, unvernetzte, lagerstabile, oberhalb von 50°C härtbare Formmasse aus einem flüssigen Reaktivsystem, einem Eindickmittel, einem Polymerisationsinitiator und üblichen Zusatzstoffen. Das Eindickmittel ist eine Kombination aus einem primären aromatischen Amin und einem Isocyanat. Die Formmassen, die insbesondere als SMC- oder BMC-Massen vorliegen, können durch Pressen, Spritzgießen oder Spritzpressen und anschließendes Aushärten zu Formteilen verarbeitet werden.

  本发明涉及一种可在 50°C 以上固化的增稠、非交联、贮存稳定的模塑化合物，由液 体反应体系、增稠剂、聚合引发剂和常规添加剂组成。增稠剂是芳香族伯胺和异氰酸酯的混合物。模塑化合物，尤其是 SMC 或 BMC 化合物，可通过压制、注塑或注塑压缩成型以及随后的固化工艺加工成模塑部件。
• Thickened moulding resin composition
  申请人：GENCORP INC.

  公开号：EP0343764A2

  公开（公告）日：1989-11-29

  Sheet molding compounds are thickened (or maturated) via "in situ" formation of polyureas made from aromatic primary diamines with reduced basicity and diisocyanates. The molding compounds, which can optionally contain mineral fillers such as chopped glass fiber, are generally based upon unsaturated polyester resins having a high percentage of hydroxyl end groups, polymerizable vinyl compounds such as styrene, and the like. The thickened compositions are tack-free and compression moldable after less than one day, typically after less than several hours, into permanently shaped, strong rigid articles, such as automotive body parts. A viscosity plateau is reached and maintained by the maturated compounds of the present invention for extended periods of time, e.g., several weeks.

  片状模塑料通过 "原位 "形成由碱性降低的芳香族伯二胺和二异氰酸酯制成的聚脲来增稠（或熟化）。成型化合物可选择含有矿物填料（如切碎的玻璃纤维），一般基于具有高比例羟基末端基团的不饱和聚酯树脂、可聚合乙烯基化合物（如苯乙烯）等。增稠后的组合物无粘性，可在一天内（通常在几小时内）压缩成型为永久成形的坚固硬质物品，如汽车车身部件。本发明的熟化化合物可在较长时间（如数周）内达到并保持粘度稳定状态。
• Active-matrix liquid crystal display
  申请人：HITACHI, LTD.

  公开号：EP0806698A1

  公开（公告）日：1997-11-12

  An active-matrix liquid crystal display device employing the in-plane switching mode in which an electric field substantially parallel to the substrate surface is applied to the liquid crystals, characterized by weak torsional anchoring of the liquid crystal molecules (6) and the alignment layer surface at the liquid crystal/alignment layer interface to an extent that the extrapolation length which expresses the strength of said torsional anchoring will become not less than 10% of the gap between the substrates. For obtaining such weak torsional anchoring, an organic alignment layer (5) comprising a polymer and/or oligomer having long-chain alkylene and/or fluoro groups, or an inorganic alignment layer formed by oblique evaporation technique, or a photo-reactive alignment layer formed by linearly polarized light irradiation is used.

  一种采用平面内开关模式的有源矩阵液晶显示装置，在这种模式下，电场基本上平行于基板表面施加到液晶上，其特征是液晶分子（6）和配向层表面在液晶/配向层界面处的扭转锚定很弱，以至于表示所述扭转锚定强度的外推长度将不小于基板之间间隙的 10%。为获得这种微弱的扭转锚定，可使用由具有长链亚烷基和/或氟基团的聚合物和/或低聚物组成的有机配位层 (5)，或通过斜蒸发技术形成的无机配位层，或通过线偏振光照射形成的光反应配位层。
• Synthesis, characterization and morphological studies of some novel siloxane-based block copolymeric materials containing organometallic as well as organic polyesteramides
  作者：Muhammad Saif Ullah Khan、Zareen Akhter、Naseer Iqbal、Mohammad Siddiq

  DOI：10.1016/j.jorganchem.2013.08.002

  日期：2013.11

  A series of semi-aromatic diamine monomers (1,m-bis (4-amino benzoyloxy) alkanes; m = 2-6) having in-built ester linkages with variable methylene spacers were synthesized in two steps from aliphatic diols and p-nitrobenzoyl chloride and characterized by their melting points, elemental analysis, FTIR, H-1 and C-13 NMR spectroscopic studies. The diamines were then polymerized in-situ with ferrocene-based organometallic and terephthaloyl-as well as isophthaloyl-based organic acyl chlorides along with telechelic polydimethylsiloxane oligomer to produce a novel set of ferrocene-containing siloxane-based block copolymers and their organic analogues. The corresponding polyesteramides of the synthesized copolymers, without siloxane segment, were also prepared for comparative studies. The structural features of the organometallic and organic block copolymers along with their respective polyesteramides were confirmed by their physical properties and spectroscopic studies. The molecular parameters of all these materials were determined by static laser light scattering (LLS) technique and glass transition temperatures (T-g) were obtained by differential scanning calorimetry (DSC). The materials were soluble in sulphuric acid and partially soluble in common organic solvents at room temperature, yet become readily soluble upon N-trifluoroacetylation. The morphological information of the synthesized materials was obtained by X-ray diffraction and surface studies (SEM and AFM). (C) 2013 Elsevier B.V. All rights reserved.