N-(1-氧代癸基)-DL-蛋氨酸 | 21394-48-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: N-(1-氧代癸基)-DL-蛋氨酸
• 英文名称: N-(1-oxodecyl)-DL-methionine
• 英文别名: DL-4-Methylmercapto-2-decanoylamino-buttersaeure；2-(Decanoylamino)-4-methylsulfanylbutanoic acid
• CAS: 21394-48-9
• 化学式: C₁₅H₂₉NO₃S
• 分子量: 303.466
• InChiKey: PECAWSDTQIFOPF-UHFFFAOYSA-N

物化性质

• 沸点：
  509.5±45.0 °C(Predicted)
• 密度：
  1.042±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  20
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  91.7
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2930909090

反应信息

• 作为反应物：
  描述：

  5-氟-2',3'-异亚丙基尿苷 、 N-(1-氧代癸基)-DL-蛋氨酸 生成 [(2R,3S,4R,5R)-5-(5-fluoro-2,4-dioxopyrimidin-1-yl)-3,4-dihydroxyoxolan-2-yl]methyl 2-(decanoylamino)-4-methylsulfanylbutanoate
  参考文献：
  名称：

  EHNDO, TAKEHSI;SAKAI, KATSUESI;NAGAKIE, AKIRA;INAMOTO, JOSITAKA;TEHSIGAXA+

  摘要：

  DOI：
• 作为产物：
  描述：

  癸酰氯 、 DL-蛋氨酸 在 sodium hydroxide 作用下， 生成 N-(1-氧代癸基)-DL-蛋氨酸
  参考文献：
  名称：

  Sciortino; Du Ban, Bollettino Chimico Farmaceutico, 1968, vol. 107, # 8, p. 498 - 505

  摘要：

  DOI：

文献信息

• Organic compounds
  申请人：Givaudan S.A.

  公开号：US10836712B2

  公开（公告）日：2020-11-17

  A flavour composition comprising a compound according to the formula (I) or edible salts thereof, wherein R1 is an alkyl residue containing 6 to 20 carbon atoms, or an alkene residue containing from 9 to 25 carbon atoms with 1 to 6 double bonds, R1 together with the carbonyl group to which it is attached is a residue of a carboxylic acid, and NR2R3, in which R3 is H or together with R2 and the N-atom to which they are attached, a 5-membered ring, is a residue of an amino acid, in particular a proteinogenic amino acid, ornithine, gamma-aminobutyric acid or beta alanine, or a 1-amino cycloalkyl carboxylic acid.

  一种包含符合式(I)的化合物或其可食用盐的风味组合物，其中R1是含有6至20个碳原子的烷基残基，或者含有9至25个碳原子且具有1至6个双键的烯烃残基，R1与其连接的羰基一起是羧酸的残基，NR2R3中，R3为H或与R2和它们连接的N原子一起是一个5元环的残基，是一种氨基酸的残基，特别是一种蛋白质原性氨基酸、鸟氨酸、γ-氨基丁酸或β-丙氨酸，或者是一种1-氨基环烷基羧酸的残基。
• N-Acyl-Amino Acid Derivatives for Improvement of the Flavour Profile Edible Compositions
  申请人：Givaudan S.A.

  公开号：US20150086694A1

  公开（公告）日：2015-03-26

  The use of a compound according to formula (I) or the edible salts thereof in an edible composition to mask or modulate an undesired taste or off-taste contained in the edible composition wherein R 1 is an alkyl residue containing 6 to 20 carbon atoms, or an alkene residue containing from 9 to 25 carbon atoms with 1 to 6 double bonds, R 1 together with the carbonyl group to which it is attached is a residue of a carboxylic acid, and NR 2 R 3 , in which R 3 is H or together with R 2 and the N-atom to which they are attached, a 5-membered ring, is a residue of an amino acid, in particular a proteinogenic amino acid, ornithine, gamma-aminobutyric acid or beta alanine, or a 1-amino cycloalkyl carboxylic acid.

  根据公式（I）或其可食用盐在可食用组合物中的使用，以掩盖或调节可食用组合物中所含的不良味道或异味，其中R1是含6至20个碳原子的烷基残基，或含有1至6个双键的9至25个碳原子的烯烃残基，R1与其附着的羰基基团一起是羧酸的残基，而NR2R3中，R3为H或与R2和它们所附着的N原子一起，形成一个5元环，是氨基酸的残基，特别是蛋白质原氨基酸、鸟氨酸、γ-氨基丁酸或β-丙氨酸，或1-氨基环烷基羧酸的残基。
• N-acyl-amino acid derivatives for improvement of the flavor profile of edible compositions
  申请人：Givaudan S.A.

  公开号：US10856563B2

  公开（公告）日：2020-12-08

  The use of a compound according to formula (I) or the edible salts thereof in an edible composition to mask or modulate an undesired taste or off-taste contained in the edible composition wherein R1 is an alkyl residue containing 6 to 20 carbon atoms, or an alkene residue containing from 9 to 25 carbon atoms with 1 to 6 double bonds, R1 together with the carbonyl group to which it is attached is a residue of a carboxylic acid, and NR2R3, in which R3 is H or together with R2 and the N-atom to which they are attached, a 5-membered ring, is a residue of an amino acid, in particular a proteinogenic amino acid, ornithine, gamma-aminobutyric acid or beta alanine, or a 1-amino cycloalkyl carboxylic acid.

  在可食用组合物中使用式(I)化合物或其食用盐，以掩盖或调节可食用组合物中所含的不良味道或异味 其中 R1 是含有 6 至 20 个碳原子的烷基残基，或含有 9 至 25 个碳原子并带有 1 至 6 个双键的烯基残基，R1 与所连接的羰基一起是羧酸残基，以及 NR2R3、是氨基酸残基，特别是蛋白氨基酸、鸟氨酸、γ-氨基丁酸或 β-丙氨酸，或 1-氨基环烷基羧酸。
• N-acylated methionine derivatives as food flavoring compounds
  申请人：Givaudan S.A.

  公开号：US10913922B2

  公开（公告）日：2021-02-09

  A flavour composition comprising a compound of formula (I) and edible salts thereof, wherein R1 is an alkyl residue containing 6 to 20 carbon atoms, or an alkene residue containing from 9 to 25 carbon atoms with 1 to 6 double bonds, R1 together with the carbonyl group to which it is attached is a residue of a carboxylic acid.

  一种香料组合物，包含式 (I) 的化合物 及其食用盐、 其中 R1 是含有 6 至 20 个碳原子的烷基残基，或含有 9 至 25 个碳原子并带有 1 至 6 个双键的烯基残基，R1 与所连接的羰基一起是羧酸残基。
• In or relating to organic compounds
  申请人：Givaudan SA

  公开号：US11524933B2

  公开（公告）日：2022-12-13

  A flavour composition comprising a compound according to the formula (I) or edible salts thereof, wherein R 1 is alkyl residue containing 6 to 20 carbon atoms, or an alkene residue containing from 9 to 25 carbon atoms with 1 to 6 double bonds, R 1 together with the carbonyl to which it is attached is a residue carboxylic acid, and NR 2 R 3 , in which R 3 is H or together with R 2 and the N-atom to which they are attached, a 5-membered ring, is a residue of an amino acid, in particular proteinogenic amino acid, ornithine, gamma-aminobutyric acid or beta alanine, or a 1-amino cycloalkyl carboxylic acid.

  一种香料组合物，包含根据式 (I) 的化合物或其食用盐、 其中 R 1 是含有 6 至 20 个碳原子的烷基残基，或含有 9 至 25 个碳原子并带有 1 至 6 个双键的烯基残基，R 1 连同其所连接的羰基是羧酸残基，而 NR 2 R 3 ，其中 R 3 是 H 或与 R 2 是氨基酸残基，特别是蛋白氨基酸、鸟氨酸、γ-氨基丁酸或 β-丙氨酸，或 1-氨基环烷基羧酸。