1,5,6,10-tetrathiadecane | 88300-05-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 有机二硫化物
• 英文名称: 1,5,6,10-tetrathiadecane
• 英文别名: bis-(3-mercapto-propyl)-disulfide；Bis-(3-mercapto-propyl)-disulfid；3.3'-Dimercapto-dipropyldisulfid；3-(3-Sulfanylpropyldisulfanyl)propane-1-thiol
• CAS: 88300-05-4
• 化学式: C₆H₁₄S₄
• 分子量: 214.441
• InChiKey: KTJKAUMRBSAQLR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  10
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,5,6,10-tetrathiadecane 在 碘 、 三乙胺 作用下， 以 氯仿 为溶剂， 反应 6.0h， 生成 1,2,6,7-四硫杂环癸烷
  参考文献：
  名称：

  Goodrow, Marvin H.; Olmstead, Marilyn M.; Musker, Kenneth W., Phosphorus and Sulfur and the Related Elements, 1983, vol. 16, p. 299 - 302

  摘要：

  DOI：
• 作为产物：
  描述：

  福多司坦杂质 在 sodium hydroxide 、 氢溴酸 、 硫脲 作用下， 生成 1,5,6,10-tetrathiadecane
  参考文献：
  名称：

  Goodrow, Marvin H.; Olmstead, Marilyn M.; Musker, Kenneth W., Phosphorus and Sulfur and the Related Elements, 1983, vol. 16, p. 299 - 302

  摘要：

  DOI：

文献信息

• Vis/NIR light driven mild and clean synthesis of disulfides in the presence of Cu₂(OH)PO₄ under aerobic conditions
  作者：Sk. Sheriff Shah、S. Karthik、N. D. Pradeep Singh

  DOI：10.1039/c5ra05138j

  日期：——

  A highly efficient one-pot strategy has been developed for the synthesis of disulfide in the presence of air under the irradiation of Vis/NIR light.

  已开发出一种高效的一锅法合成二硫化物的策略，在可见光/近红外光照射下在空气存在下进行。
• Oxidation of thiols with metal nitrates supported on TAFF
  作者：Gabriel Arroyo、Roberto Osnaya、Tonatiuh Cruz、Amparo Londoño、Cecilio Álvarez、Francisco Delgado、Ricardo Santiago、René Miranda

  DOI：10.1002/hc.10138

  日期：——

  Twelve thiols were readily oxidized to the corresponding disulfides by means of four metal nitrates supported on TAFF, a bentonitic clay, under mild conditions. However, in some cases, thioethers and other interesting by-products were detected. Some of the disulfides showed antimicotical activities against Aspergillus fumigatus, Aspergillus niger, Aspergillus candidus, Microsporum gypseum, Candida

  在温和条件下，通过负载在 TAFF（一种膨润土）上的四种金属硝酸盐，12 种硫醇很容易被氧化成相应的二硫化物。然而，在某些情况下，会检测到硫醚和其他有趣的副产品。一些二硫化物显示出对烟曲霉、黑曲霉、念珠菌、石膏小孢子菌、白色念珠菌和新型隐球菌的抗菌活性 © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:262-2065; 在线发表于 Wiley InterScience (www.interscience.wiley.com)。DOI 10.1002/hc.10138
• POLYMERIZABLE COMPOSITION AND NOVEL ALKYNE COMPOUND
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20180066082A1

  公开（公告）日：2018-03-08

  Provided is a polymerizable composition including an alkyne compound represented by the following general formula (1): wherein, in general formula (1), X 1 and X 2 represent a sulfur atom, an oxygen atom, or an NH group and may be the same or different from each other, Q represents an alkylene group having 1 or 2 carbon atoms, a carbonyl group, or a thiophenylene group in which one of carbon atoms is substituted by an antimony atom, R 1 and R 2 represent an alkylene group having 1 or 2 carbon atoms and may be the same or different from each other, and m and n each represent 0 or 1.

  提供的是一种可聚合组合物，其中包括以下一般式（1）所表示的炔基化合物：在一般式（1）中，X1和X2代表硫原子、氧原子或NH基团，可以相同也可以不同，Q代表具有1或2个碳原子的烷基基团、酰基基团或一种硫代苯基团，其中一个碳原子被锑原子取代，R1和R2代表具有1或2个碳原子的烷基基团，可以相同也可以不同，m和n分别表示0或1。
• Metal Thietane Compound, Polymerizable Composition Containing the Compound, Resin and Use of the Resin
  申请人：Murakami Masakazu

  公开号：US20130018169A1

  公开（公告）日：2013-01-17

  Polymerizable compositions containing at least one metal thietane compound represented by general formulas (110), (201) or (120), respectively, wherein said formulas are as follows: and wherein the identified moieties and n, p, q and r are defined.

  含有至少一种由通式（110）、（201）或（120）表示的金属噻吩化合物的聚合物组合物，其中所述的通式如下：其中所识别的基团和n、p、q和r已被定义。
• METAL THIETANE COMPOUND, POLYMERIZABLE COMPOSITION CONTAINING THE COMPOUND, RESIN AND USE OF THE RESIN
  申请人：Murakami Masakazu

  公开号：US20100240862A1

  公开（公告）日：2010-09-23

  Disclosed is a metal thietane compound represented by the following general formula (120), (wherein, in the above general formula (120), M is a member selected from the group consisting of Bi, Sb, Ti, Zr and Ta; X 1 and X 2 are each independently a sulfur atom or an oxygen atom; R 1 is a divalent organic group; the bond between M and T shown by a dotted line and a solid line represents a single or double bond; m is an integer of 0 or 1 or more; n is the number of valence of M; and p is an integer of equal to or more than 1 and equal to or less than n, provided that when r is 1, q is 0 and Y is a monovalent inorganic or organic group; when r is 1 and n-p-q is 2 or more, a plurality of Ys contained are each independently selected from monovalent inorganic or organic groups; when r is 1 and n-p-q is 2 or more, a plurality of Ys may be bonded to each other to form a ring containing M; when r is 2, n-p-q is 1 or 2 and Y is a divalent group; when r is 2 and n-p-q is 2, two Ys may form a ring together with two Ms; and when r is 2 and q is 2, a plurality of Ts contained are each independently selected from inorganic or organic groups).

  公开了一种金属硫代环烷化合物，其通式如下（120），其中，在上述通式（120）中，M是从Bi、Sb、Ti、Zr和Ta组成的群体中选择的成员；X1和X2分别是硫原子或氧原子；R1是二价有机基团；M和T之间的键由虚线和实线表示，表示单键或双键；m是0或1或更多的整数；n是M的化合价数；p是大于或等于1且小于或等于n的整数，其中当r为1时，q为0且Y为一价无机或有机基团；当r为1且n-p-q为2或更多时，所含的多个Y各自独立地选择自一价无机或有机基团；当r为1且n-p-q为2或更多时，多个Y可以相互连接形成含M的环；当r为2时，n-p-q为1或2且Y为二价基团；当r为2且n-p-q为2时，两个Y可以与两个M一起形成环；当r为2且q为2时，所含的多个T各自独立地选择自无机或有机基团。