bis-(4-methyl-[2]quinolyl)-sulfide | 102007-55-6

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: bis-(4-methyl-[2]quinolyl)-sulfide
• 英文别名: Bis-(4-methyl-[2]chinolyl)-sulfid；4-Methyl-2-(4-methylquinolin-2-yl)sulfanylquinoline
• CAS: 102007-55-6
• 化学式: C₂₀H₁₆N₂S
• 分子量: 316.426
• InChiKey: CHPSBXBCIHINDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  51.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  bis-(4-methyl-[2]quinolyl)-sulfide 在 水 、 双氧水 、 溶剂黄146 作用下， 生成 bis-(4-methyl-[2]quinolyl)-sulfone
  参考文献：
  名称：

  Monti et al., Gazzetta Chimica Italiana, 1959, vol. 89, p. 1097,1098, 1100

  摘要：

  DOI：
• 作为产物：
  描述：

  4-甲基喹啉-2-硫酮 、 4-甲基-2-氯-喹啉 生成 bis-(4-methyl-[2]quinolyl)-sulfide
  参考文献：
  名称：

  Monti et al., Gazzetta Chimica Italiana, 1959, vol. 89, p. 1097,1098, 1100

  摘要：

  DOI：

文献信息

• [EN] HARDNESS STABILIZATION BY MERCAPTOPYRIDINES<br/>[FR] STABILISATION DE LA DURETE AU MOYEN DE MERCAPTOPYRIDINES
  申请人：FLEXSYS BV

  公开号：WO2001016226A1

  公开（公告）日：2001-03-08

  The invention relates to a sulfur vulcanization process comprising (a) a non-productive stage of mixing of a rubber composition comprising styrene-butadiene rubber, (b) a productive stage of mixing of a rubber composition further comprising sulfur and a vulcanization accelerator, and (c) vulcanization of said rubber composition and is characterized in that in the non-productive or productive stage of mixing there is added 0.1 to 1 phr of a hardness stabilizing coagent according to any one of formulae (I)-(IV) wherein R?1, R2, and R3¿ independently represent H or a C¿1?-C5 hydrocarbon group, optionally containing one or more oxygen, nitrogen or sulfur atoms, R?1 and R2¿, provided that R1 is in the 4-position, or R?2 and R3¿ together with the carbon atoms to which they are attached may form a 5 or 6-membered ring, said ring optionally being substituted with a C¿1?-C5 hydrocarbon group, said group optionally containing one or more oxygen, nitrogen or sulfur atoms, n is 1 to 4, M is selected from Na, Zn, Mg, AL, Fe and Te, and x is 1 to 4. The invention also relates to an article of manufacture, such as a pneumatic tyre, comprising the rubber vulcanizate obtained by said process.
• Monti et al., Gazzetta Chimica Italiana, 1959, vol. 89, p. 1097,1098, 1100
  作者：Monti et al.

  DOI：——

  日期：——