3-Methyl-3-Pentyl Methacrylate | 63715-93-5

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 3-Methyl-3-Pentyl Methacrylate
• 英文别名: 3-methylpentan-3-yl 2-methylprop-2-enoate
• CAS: 63715-93-5
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: DDSLEYXSLOZJKY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲基丙烯酰氯 以50%的产率得到
  参考文献：
  名称：

  BANKS A. R.; FIBIGER R. F.; JONES T., J. ORG. CHEM., 1977, 42, NO 24, 3965-3966

  摘要：

  DOI：

文献信息

• Acrylate ester monomer production
  申请人：University Patents, Inc.

  公开号：US04258204A1

  公开（公告）日：1981-03-24

  Acrylate ester monomers are produced in high yield and without polymerization by reacting an .alpha.,.beta.-unsaturated organic acid halide and a hydroxyl containing organic compound in the presence of molecular sieves. In the absence of molecular sieves the same reactants produce the monomer ester products in low yield and/or form polymers.

  丙烯酸酯单体可以在分子筛的存在下，通过将α，β-不饱和有机酸卤化物和含有羟基的有机化合物反应而高产率地生成，而且不会聚合。在没有分子筛的情况下，相同的反应物会产生低产率的单体酯产品和/或形成聚合物。
• Coating Composition, Optical Film, Antireflective, Film, Polarizing Plate, And Display Device Using The Same
  申请人：Yoshizawa Masataka

  公开号：US20080038561A1

  公开（公告）日：2008-02-14

  There is provided a coating composition capable of improving evenness in drying and evenness in airing and causing no impairment of evenness in coating, which is useful for an antireflective film having high uniformity in surface conditions and attaining sufficient antireflection performance and for a polarizing plate and a display device each using such an antireflective film. As the coating composition as mentioned above, a coating composition including a fluoroaliphatic group-containing copolymer that includes a repeating unit corresponding to the fluoroaliphatic group-containing monomer represented by the following formula (1) and a repeating unit corresponding to the monomer represented by the following formula (2) was found: in formula [1], R 0 represents a hydrogen atom, a halogen atom or a methyl group; L represents a divalent linkage group; and n represents an integer of 1 to 18, and in formula [2], R 11 represents a hydrogen atom, a halogen atom or a methyl group; L 11 represents a divalent linkage group; and R 13 , R 14 and R 15 each represents a 1-20C linear, branched or cyclic alkyl group which may have a substituent.

  提供了一种涂层组合物，能够提高干燥均匀性和通风均匀性，且不会影响涂层均匀性，该组合物对于具有高表面条件均匀性和达到足够抗反射性能的抗反射膜以及使用此类抗反射膜的偏光板和显示装置非常有用。作为上述涂层组合物，发现包括重复单元对应于以下公式（1）所表示的含氟脂肪基单体的含氟脂肪基共聚物和对应于以下公式（2）所表示的单体的重复单元的涂层组合物：在公式[1]中，R0表示氢原子、卤素原子或甲基基团；L表示双价连接基团；n表示1到18的整数，在公式[2]中，R11表示氢原子、卤素原子或甲基基团；L11表示双价连接基团；R13、R14和R15分别表示1-20C线性、支链或环状烷基，可以有取代基。
• PHOTORESIST AND COATED SUBSTRATE COMPRISING SAME
  申请人：Wang Deyan

  公开号：US20140065540A1

  公开（公告）日：2014-03-06

  A polymer includes the polymerized product of monomers including a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a, L 1 , LN, R a , R b , R c , and X are defined herein. The polymer is a useful component of a photoresist composition.

  一种聚合物包括单体的聚合产物，其中包括一种含有氮的单体，其化学式为（Ia）、化学式为（Ib）或化学式（Ia）和（Ib）的组合，并且还包括具有化学式（II）的酸解保护单体：其中a、L1、LN、Ra、Rb、Rc和X的定义如本文所述。该聚合物是光阻组合物的有用组分。
• SURFACE ACTIVE ADDITIVE AND PHOTORESIST COMPOSITION COMPRISING SAME
  申请人：Wang Deyan

  公开号：US20130137035A1

  公开（公告）日：2013-05-30

  A polymer comprises the polymerized product of monomers comprising a nitrogen-containing monomer comprising formula (Ia), formula (Ib), or a combination of formulas (Ia) and (Ib), and an acid-deprotectable monomer having the formula (II): wherein a is 0 or 1, each R a is independently H, F, C 1-10 alkyl, or C 1-10 fluoroalkyl, L 1 is a straight chain or branched C 1-20 alkylene group, or a monocyclic, polycyclic, or fused polycyclic C 3-20 cycloalkylene group, each R b is independently H, C 1-10 alkyl, C 3-20 cycloalkyl, C 3-20 heterocycloalkyl, an aliphatic C 5-20 oxycarbonyl, or a C 1-30 acyl group optionally including a heteroatom substituent group, where each R b is separate or at least one R b is attached to an adjacent R b ; LN is a nitrogen-containing monocyclic, polycyclic, or fused polycyclic C 3-20 heterocycloalkylene group, and X is H, C 1-10 alkyl, aliphatic C 5-20 oxycarbonyl, or a C 1-30 acyl group optionally including a heteroatom substituent group; and each R c is independently C 1-10 alkyl, C 3-20 cycloalkyl, or C 3-20 heterocycloalkyl, wherein each R c is separate or at least one R c is attached to an adjacent R c .

  一种聚合物包括由单体聚合而成的产物，所述单体包括式（Ia）、式（Ib）或式（Ia）和（Ib）的组合所包含的含氮单体，以及具有式（II）的酸去保护单体：其中a为0或1，每个Rais独立地为H、F、C1-10烷基或C1-10氟烷基，L1为直链或支链C1-20烷基，或单环、多环或融合多环C3-20环烷基，每个Rbis独立地为H、C1-10烷基、C3-20环烷基、C3-20杂环烷基、脂肪族C5-20氧羰基或C1-30酰基，可包括一个杂原子取代基，其中每个Rbis分离或至少一个Rbis连接到相邻的Rb上；LN为含氮单环、多环或融合多环C3-20杂环烷基，X为H、C1-10烷基、脂肪族C5-20氧羰基或C1-30酰基，可包括一个杂原子取代基；每个Rcis独立地为C1-10烷基、C3-20环烷基或C3-20杂环烷基，其中每个Rcis分离或至少一个Rcis连接到相邻的Rc上。
• HIGH VISCOSITY INDEX COMB POLYMER VISCOSITY MODIFIERS AND METHODS OF MODIFYING LUBRICANT VISCOSITY USING SAME
  申请人：Infineum International Limited

  公开号：EP3839017A1

  公开（公告）日：2021-06-23

  A comb copolymer viscosity modifier may be made by polymerization comprising at least, or consisting essentially of, the following monomers: (a) a hydrogenated polybutadiene-based (alk)acrylate ester macromonomer (which repeat units may comprise from 7.0 wt% to 18 wt% of the repeat units of the comb copolymer viscosity modifier); (b) a C3-C8 alkyl (alk)acrylate ester monomer (which repeat units may comprise from 40 wt% to 71 wt% or from 45 wt% to 64 wt% of the repeat units of the comb copolymer viscosity modifier); and (c) a C12-C24 alkyl (alk)acrylate ester monomer, wherein repeat units based on the C12-C24 alkyl (alk)acrylate ester monomer comprise at least 21.0 wt% (and optionally up to 35.0 wt%) of repeat units of the comb copolymer viscosity modifier. Lubricant compositions comprising the comb copolymer viscosity modifier, as well as uses thereof and methods for modifying viscosity, are also contemplated herein.

  梳状共聚物粘指剂可通过聚合制成，至少或主要由以下单体组成：(a) 氢化聚丁二烯基（烷基）丙烯酸酯大单体（其重复单元可占梳状共聚物粘指剂重复单元的 7.0 wt% 至 18 wt%）；(b) C3-C8 烷基（烷基）丙烯酸酯单体（其重复单元可占梳状共聚物粘指剂重复单元的 7.(b) C3-C8 烷基(烷基)丙烯酸酯单体(其重复单元可占梳状共聚物粘指剂重复单元的 40% 至 71% 或 45% 至 64%)；(c) C12-C24 烷基(烷基)丙烯酸酯单体，其中基于 C12-C24 烷基(烷基)丙烯酸酯单体的重复单元占至少 21.0 wt%（可选最多 35.0 wt%）的组合共聚物粘指剂重复单元。本文还考虑了包含梳状共聚物粘指剂的润滑剂组合物及其用途和粘度调节方法。