Ph2PCH2CH2O-2,3,5,6-C6(CH3)4H | 890881-54-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: Ph2PCH2CH2O-2,3,5,6-C6(CH3)4H
• 英文别名: Diphenyl-[2-(2,3,5,6-tetramethylphenoxy)ethyl]phosphane；diphenyl-[2-(2,3,5,6-tetramethylphenoxy)ethyl]phosphane
• CAS: 890881-54-6
• 化学式: C₂₄H₂₇OP
• 分子量: 362.452
• InChiKey: LKWSPHQZZGPHBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二氯甲烷 、 1,4-bis(diphenylphosphino)ethylthiobenzene 、 Ph2PCH2CH2O-2,3,5,6-C6(CH3)4H 、 chloro(1,5-cyclooctadiene)rhodium(I) dimer 以 二氯甲烷 为溶剂， 以77%的产率得到
  参考文献：
  名称：

  Triple-Decker Complexes Formed via the Weak Link Approach

  摘要：

  Through the weak link approach and a halide-induced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.

  DOI：

  10.1021/om0602310

文献信息

• Triple-Decker Complexes Formed via the Weak Link Approach
  作者：You-Moon Jeon、Jungseok Heo、Aaron M. Brown、Chad A. Mirkin

  DOI：10.1021/om0602310

  日期：2006.5.1

  Through the weak link approach and a halide-induced ligand rearrangement process, semi-open and condensed triple-decker complexes (TDCs) were prepared and fully characterized. These triple-decker structures with tailorable layers through choice of hemilabile ligand starting materials can be chemically opened and closed to expose the interior layer in a reversible fashion using small-molecule and elemental anion ligand substitution reactions.