N¹-(2-Amino-ethyl)-N¹-(4-vinyl-benzyl)-ethane-1,2-diamine | 46734-05-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N¹-(2-Amino-ethyl)-N¹-(4-vinyl-benzyl)-ethane-1,2-diamine
• 英文别名: 1,2-Ethanediamine, N-(2-aminoethyl)-N-[(4-ethenylphenyl)methyl]-；N'-(2-aminoethyl)-N'-[(4-ethenylphenyl)methyl]ethane-1,2-diamine
• CAS: 46734-05-8
• 化学式: C₁₃H₂₁N₃
• 分子量: 219.33
• InChiKey: XFMMOCFJFBCOBM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  16
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  55.3
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  4-氯甲基苯乙烯 在 potassium carbonate 、 一水合肼 作用下， 以 乙醇 、 乙腈 为溶剂， 反应 42.0h， 生成 N¹-(2-Amino-ethyl)-N¹-(4-vinyl-benzyl)-ethane-1,2-diamine
  参考文献：
  名称：

  Selective discrimination of closely related monosaccharides at physiological pH by a polymeric receptor

  摘要：

  High selectivity for glucose by a polymeric receptor at physiological pH over other 1,2-cis-diols, namely mannose and galactose, and over a non-imprinted control polymer is reported. The shape selectivity of the imprinted cavity of the polymer has been examined in competing and non-competing rebinding experiments under saturation conditions applying weak binding interactions at physiological pH. The influence of the orientation of the functional groups during polymerisation resulting in the observed high shape selectivity of the cavity has been discussed. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(01)00117-x

文献信息

• Selective discrimination of closely related monosaccharides at physiological pH by a polymeric receptor
  作者：Susanne Striegler

  DOI：10.1016/s0040-4020(01)00117-x

  日期：2001.3

  High selectivity for glucose by a polymeric receptor at physiological pH over other 1,2-cis-diols, namely mannose and galactose, and over a non-imprinted control polymer is reported. The shape selectivity of the imprinted cavity of the polymer has been examined in competing and non-competing rebinding experiments under saturation conditions applying weak binding interactions at physiological pH. The influence of the orientation of the functional groups during polymerisation resulting in the observed high shape selectivity of the cavity has been discussed. (C) 2001 Elsevier Science Ltd. All rights reserved.