N,N'-bis-1-hexylheptyl-bis-2,2'-(4-dimethylaminophenyl)imidazolo[4,5:b;4,5:e]naphthalenetetracarboxylic-1,8:4,5-biscarboximide | 1252975-14-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: N,N'-bis-1-hexylheptyl-bis-2,2'-(4-dimethylaminophenyl)imidazolo[4,5:b;4,5:e]naphthalenetetracarboxylic-1,8:4,5-biscarboximide
• 英文别名: 4,14-Bis[4-(dimethylamino)phenyl]-9,19-di(tridecan-7-yl)-3,5,9,13,15,19-hexazahexacyclo[9.9.2.02,6.07,22.012,16.017,21]docosa-1,3,6,11,13,16,21-heptaene-8,10,18,20-tetrone；4,14-bis[4-(dimethylamino)phenyl]-9,19-di(tridecan-7-yl)-3,5,9,13,15,19-hexazahexacyclo[9.9.2.02,6.07,22.012,16.017,21]docosa-1,3,6,11,13,16,21-heptaene-8,10,18,20-tetrone
• CAS: 1252975-14-6
• 化学式: C₅₈H₇₆N₈O₄
• 分子量: 949.293
• InChiKey: YNJJRIZSSJZJSF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.5
• 重原子数：
  70
• 可旋转键数：
  26
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.52
• 拓扑面积：
  139
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  2,7-bis(1-hexylheptyl)benzo[lmn][3,8]phenanthroline-1,3,6,8-tetraone 、 4-(二甲胺基)苄腈 在 sodium amide 作用下， 反应 2.0h， 以9%的产率得到N,N'-bis-1-hexylheptyl-2-(4-dimethylaminophenyl)imidazolo-[4,5:b]naphthalenetetracarboxylic-1,8:4,5-biscarboximide
  参考文献：
  名称：

  Laterally Extended Naphthalene Tetracarboxylic Bisimides

  摘要：

  The colorless naphthalene tetracarboxylic bisimides were laterally extended with imidazole rings to give colored and highly fluorescent materials Donor-substituted phenyl groups at the imidazole rings cause further bathochromic shifts in fluorescence where the strong solvent influence in the spectra is typical for a TICT process Applications are discussed

  DOI：

  10.1021/jo101520a

文献信息

• Laterally Extended Naphthalene Tetracarboxylic Bisimides
  作者：Heinz Langhals、Simon Kinzel

  DOI：10.1021/jo101520a

  日期：2010.11.19

  The colorless naphthalene tetracarboxylic bisimides were laterally extended with imidazole rings to give colored and highly fluorescent materials Donor-substituted phenyl groups at the imidazole rings cause further bathochromic shifts in fluorescence where the strong solvent influence in the spectra is typical for a TICT process Applications are discussed