N,N,N',N'',N'''-pentamethyldiethylenetriamine | 28403-93-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'',N'''-pentamethyldiethylenetriamine
• 英文别名: PMDETA；N,N,N',N',N"-pentamethyldiethylenetriamine；N'-[(dimethylamino)methyl]-N,N,N'-trimethylmethanediamine
• CAS: 28403-93-2
• 化学式: C₇H₁₉N₃
• 分子量: 145.248
• InChiKey: RNOLPHKZUZQNJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N,N,N',N'',N'''-pentamethyldiethylenetriamine 、 bis(2-picolyl)phenylphosphine 在 正丁基锂 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 24.25h， 以53%的产率得到[(PMDETA)Li{C(H)Py}P(CH₂Py)Ph]
  参考文献：
  名称：

  基于电荷密度研究判断二-2-吡啶甲基苯基膦的配位能力

  摘要：

  [PhP(CH2Py)2LiCl]2 (2) 的受阻反应性与无氯化锂配体 PhP(CH2Py)2 (Py = 2-pyridyl) (1) 的配位行为相比，可以通过实验电子密度来阐明学习。根据含有双阴离子Janus Head配体[PhP(CHPy)2]2-的金属配合物的成功合成，研究了单阴离子配体[PhP{C(H)Py}(CH2Py)]-的形成和配位模式. 配体 1 分别与正丁基锂/PMDETA 和超碱性正丁基锂/NaOtBu 反应生成碱金属配合物 [(PMDETA)Li{C(H)Py}P(CH2Py)Ph] (5) 和[(PyCH2)PhP{C(H)Py}Na(Et2O)]2 (6)。

  DOI：

  10.1002/zaac.201300092
• 作为试剂：
  描述：

  2-氟苯甲醚 、 草酸二乙酯 在 正丁基锂 、 N,N,N',N'',N'''-pentamethyldiethylenetriamine 作用下， 以 四氢呋喃 、 hexanes 为溶剂， 反应 2.75h， 生成 2-(2-fluoro-3-methoxyphenyl)oxoacetic acid ethyl ester
  参考文献：
  名称：

  [EN] PROCESSES FOR THE PREPARATION OF URACIL DERIVATIVES
  [FR] PROCÉDÉS DE PRÉPARATION DE DÉRIVÉS D'URACILE

  摘要：

  本发明涉及制备促性腺激素释放激素（GnRH）受体拮抗剂结构（VI）的过程和中间体，以及其立体异构体和药用盐。

  公开号：

  WO2009062087A1

文献信息

• AROMATIC AMINE DERIVATIVES AND ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kawamura Masahiro

  公开号：US20070029927A1

  公开（公告）日：2007-02-08

  An aromatic amine derivative with a specific structure and an organic electroluminescence device which comprises at least one organic thin film layer comprising a light emitting layer sandwiched between a pair of electrode consisting of an anode and a cathode, wherein at least one of the organic thin film layer comprises the aromatic amine derivative singly or as its mixture component. The organic electroluminescence device which exhibits an enhanced current efficiency of light emission and emits blue light with a prolonged lifetime is realized.

  一种具有特定结构的芳香胺衍生物和一种有机电致发光器件，该器件至少包括一个有机薄膜层，其中包括夹在由阳极和阴极组成的一对电极之间的发光层，其中至少一个有机薄膜层包括该芳香胺衍生物单独或作为其混合组分。实现了一种具有增强的发光电流效率并且发出蓝光并具有延长寿命的有机电致发光器件。
• NOVEL POLYMERIZABLE MONOMER, AND MATERIAL FOR ORGANIC DEVICE, HOLE INJECTION/TRANSPORT MATERIAL, MATERIAL FOR ORGANIC ELECTROLUMINESCENT ELEMENT AND ORGANIC ELECTROLUMINESCENT ELEMENT EACH COMPRISING POLYMER (POLYMERIC COMPOUND) OF THE POLYMERIZABLE MONOMER
  申请人：Eida Mitsuru

  公开号：US20110315964A1

  公开（公告）日：2011-12-29

  A polymerizable monomer represented by the following formula (1) wherein at least one of Ar 1 to Ar 3 is substituted by a group represented by the following formula (2) and which is substituted by one or more groups comprising a polymerizable functional group. Ar 1 to Ar 3 are a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms, Ar 6 is a substituted or unsubstituted aryl group having 6 to 40 ring carbon atoms and Ar 4 and Ar 5 are a substituted or unsubstituted arylene group having 6 to 40 ring carbon atoms.

  由以下公式（1）表示的可聚合单体，其中Ar1至Ar3中的至少一个被以下公式（2）表示的基团取代，并且被一个或多个包含聚合功能基团的基团取代。Ar1至Ar3是具有6至40个环碳原子的取代或未取代芳基，Ar6是具有6至40个环碳原子的取代或未取代芳基，Ar4和Ar5是具有6至40个环碳原子的取代或未取代芳亚基。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE DEVICE USING THE SAME
  申请人：Kawamura Masahiro

  公开号：US20080076942A1

  公开（公告）日：2008-03-27

  An aromatic amine derivative having a specific structure. An organic electroluminescence device which is composed of one or more organic thin film layers including at least one light emitting layer sandwiched between a cathode and an anode, wherein at least one of the organic thin film layers contains the aromatic amine derivative or a material for the organic electroluminescence device singly or as its mixture component. They provide an organic electroluminescence device with an enhanced efficiency of light emission and having prolonged lifetime emitting blue light, a novel aromatic amine derivative and a material for the organic electroluminescence device realizing the device.

  具有特定结构的芳香胺衍生物。一种有机电致发光器件，由至少包括一个发光层的一个或多个有机薄膜层组成，该发光层夹在阴极和阳极之间，其中至少一个有机薄膜层包含芳香胺衍生物或有机电致发光器件的材料，单独或作为其混合成分。它们提供了一种具有增强发光效率并具有长寿命的发出蓝光的有机电致发光器件，一种新颖的芳香胺衍生物和一种实现该器件的有机电致发光器件材料。
• Process for Synthesizing Organoelemental Compounds
  申请人：Knochel Paul

  公开号：US20110084230A1

  公开（公告）日：2011-04-14

  The present application discloses a process for preparing a compound of the general formula R 1 -M 1 -A d .zLiX (I) by reacting a compound R 1 -A (III) with an element M 1 in the presence of lithium salts. The application also discloses a process for preparing a compound of the general formula R 1 m -M 3 -T m .zLiX (II) by reacting a compound R 1 -A (III) with an M 3 -containing compound in the presence of lithium salts and in the presence of an elemental metal M 2 . The metal M 3 may be selected from Al, Mn, Cu, Zn, Sn, Ti, In, La, Ce, Nd, Y, Li, Sm, Bi, Mg, B, Si and S.

  本申请公开了一种通过在锂盐存在下，将化合物R1-A(III)与元素M1反应制备出通式为R1-M1-Ad.zLiX(I)的化合物的方法。该申请还公开了一种在锂盐和元素金属M2存在下，将化合物R1-A(III)与含有M3的化合物反应制备出通式为R1m-M3-Tm.zLiX(II)的化合物的方法。金属M3可以从Al、Mn、Cu、Zn、Sn、Ti、In、La、Ce、Nd、Y、Li、Sm、Bi、Mg、B、Si和S中选择。
• Amine Compound and Organic Electroluminescent Element Employing the Same
  申请人：Watanabe Masami

  公开号：US20070243416A1

  公开（公告）日：2007-10-18

  An amine-based compound having a specific structure and an organic electroluminescence device which comprises at least one layer comprising at least a light emitting layer and is disposed between a cathode and an anode, wherein at least one layer in the organic thin film layer comprises the amine-based compound singly or as a component of a mixture. The organic electroluminescence device exhibits an excellent balance in physical properties such as a small ionization potential, a great band gap energy, a great efficiency of injection and a great mobility and excellent heat resistance and current efficiency due to the amine-based compound.

  一种具有特定结构的胺基化合物和一种有机电致发光装置，该装置包括至少一层，其中包括至少一个发光层，且位于阴极和阳极之间，其中有机薄膜层中的至少一层单独或作为混合物的组分包括胺基化合物。由于胺基化合物，有机电致发光装置在物理性能方面表现出优异的平衡，如小的电离势、大的带隙能量、大的注入效率和大的迁移率以及优异的耐热性和电流效率。