(2-Methoxy-benzyl)-(2-methylsulfanyl-phenyl)-amine | 416869-30-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (2-Methoxy-benzyl)-(2-methylsulfanyl-phenyl)-amine
• 英文别名: N-[(2-methoxyphenyl)methyl]-2-methylsulfanylaniline
• CAS: 416869-30-2
• 化学式: C₁₅H₁₇NOS
• mdl: MFCD01454075
• 分子量: 259.372
• InChiKey: RVBAGINKGUJVID-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  46.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 二氯甲烷 、 (2-Methoxy-benzyl)-(2-methylsulfanyl-phenyl)-amine 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Chromium imine and amine complexes as homogeneous catalysts for the trimerisation and polymerisation of ethylene

  摘要：

  Cr(III) complexes of tridendate imine and amine ligands with N, P, O, S donor atoms 1 and 2 have been prepared and tested as catalysts in the oligomerisation and polymerisation of ethylene giving excellent selectivity towards 1-hexene and polymerisation to polyethylene when activated with cocatalysts. X-ray structure analyses of the precatalysts 1a-c, 1i, and 2b are investigated. The metal-ligand binding in 1a and 1b is nearly the same, which leads to similar catalytic activities of these precatalysts. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.080
• 作为产物：
  描述：

  [1-(2-Methoxy-phenyl)-meth-(E)-ylidene]-(2-methylsulfanyl-phenyl)-amine 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 3.0h， 以66%的产率得到(2-Methoxy-benzyl)-(2-methylsulfanyl-phenyl)-amine
  参考文献：
  名称：

  Chromium imine and amine complexes as homogeneous catalysts for the trimerisation and polymerisation of ethylene

  摘要：

  Cr(III) complexes of tridendate imine and amine ligands with N, P, O, S donor atoms 1 and 2 have been prepared and tested as catalysts in the oligomerisation and polymerisation of ethylene giving excellent selectivity towards 1-hexene and polymerisation to polyethylene when activated with cocatalysts. X-ray structure analyses of the precatalysts 1a-c, 1i, and 2b are investigated. The metal-ligand binding in 1a and 1b is nearly the same, which leads to similar catalytic activities of these precatalysts. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2004.09.080

文献信息

• Chromium imine and amine complexes as homogeneous catalysts for the trimerisation and polymerisation of ethylene
  作者：Martin E. Bluhm、Olaf Walter、Manfred Döring

  DOI：10.1016/j.jorganchem.2004.09.080

  日期：2005.1

  Cr(III) complexes of tridendate imine and amine ligands with N, P, O, S donor atoms 1 and 2 have been prepared and tested as catalysts in the oligomerisation and polymerisation of ethylene giving excellent selectivity towards 1-hexene and polymerisation to polyethylene when activated with cocatalysts. X-ray structure analyses of the precatalysts 1a-c, 1i, and 2b are investigated. The metal-ligand binding in 1a and 1b is nearly the same, which leads to similar catalytic activities of these precatalysts. (C) 2004 Elsevier B.V. All rights reserved.