3'-fluoro-2,6-dimethylbiphenyl | 1186126-53-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3'-fluoro-2,6-dimethylbiphenyl
• 英文别名: 2-(3-Fluorophenyl)-1,3-dimethylbenzene
• CAS: 1186126-53-3
• 化学式: C₁₄H₁₃F
• 分子量: 200.256
• InChiKey: ATKNAXLRROBWSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-fluorophenyl methane sulfonate 、 2,6-二甲基苯硼酸 在 potassium phosphate 、 2-(二环己基膦)3,6-二甲氧基-2′,4′,6′-三异丙基-1,1′-联苯 、 palladium diacetate 作用下， 以 2-甲基-2-丁醇 为溶剂， 以92%的产率得到3'-fluoro-2,6-dimethylbiphenyl
  参考文献：
  名称：

  A Versatile Catalyst System for Suzuki−Miyaura Cross-Coupling Reactions of C(sp²)-Tosylates and Mesylates

  摘要：

  A catalyst system for the Suzuki-Miyaura cross-coupling reactions of aryl and vinyl tosylates and mesylates has been developed. This catalyst displays excellent functional group tolerance and allows the coupling of heteroarylboronic acids with aryl tosylates and mesylates to be performed in high yields. Moreover, reactions employing alkylboronic acids, as well as heteroaryl, vinyl, and allylic pinacol boronate esters, were conducted with high efficiencies.

  DOI：

  10.1021/ol9015892

文献信息

• CARBAZOLE-BASED COMPOUND AND ORGANIC LIGHT EMITTING DEVICE INCLUDING THE SAME
  申请人：Samsung Display Co., Ltd

  公开号：US20170213987A1

  公开（公告）日：2017-07-27

  Provided are a carbazole-based compound and an organic light-emitting device including the same. The carbazole-based compound may have the following general structure: wherein details and examples of L 1 through L 6 , R 1 through R 6 , a 1 through a 6 , and b 1 through b 6 are provided.

  提供了一种基于咔唑的化合物和包括该化合物的有机发光装置。该基于咔唑的化合物可能具有以下一般结构：其中提供了L1-L6、R1-R6、a1-a6和b1-b6的详细信息和示例。
• A Versatile Catalyst System for Suzuki−Miyaura Cross-Coupling Reactions of C(sp²)-Tosylates and Mesylates
  作者：Brijesh Bhayana、Brett P. Fors、Stephen L. Buchwald

  DOI：10.1021/ol9015892

  日期：2009.9.3

  A catalyst system for the Suzuki-Miyaura cross-coupling reactions of aryl and vinyl tosylates and mesylates has been developed. This catalyst displays excellent functional group tolerance and allows the coupling of heteroarylboronic acids with aryl tosylates and mesylates to be performed in high yields. Moreover, reactions employing alkylboronic acids, as well as heteroaryl, vinyl, and allylic pinacol boronate esters, were conducted with high efficiencies.