4,4'-aminobenzophenone-p-tosylhydrazone | 848151-27-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-aminobenzophenone-p-tosylhydrazone
• 英文别名: N-[bis(4-aminophenyl)methylideneamino]-4-methylbenzenesulfonamide
• CAS: 848151-27-9
• 化学式: C₂₀H₂₀N₄O₂S
• 分子量: 380.47
• InChiKey: OBIVNDAZGJUBFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  119
• 氢给体数：
  3
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  4,4'-aminobenzophenone-p-tosylhydrazone 、 足球烯 在 sodium methylate 作用下， 以 吡啶 、 邻二氯苯 为溶剂， 反应 0.25h， 生成 [6,6]-bis(4-aminophenyl)methanofullerene
  参考文献：
  名称：

  Design of a Series of Polythiophenes Containing C₆₀ Groups: Synthesis and Optical and Electrochemical Properties

  摘要：

  In order to develop polymers combining both acceptor and donor moieties, a series of alternating copolymers based on C-60 fullerene and oligothiophenes were synthesized. First, a diamino-functionalized fullerene was obtained by a three-step modification of 4,4'-diaminobenzophenone, followed by a BamfordStevens addition on C-60. A series of oligo-3-alkylthiophenes O3AT, with various polymer and alkyl chains lengths, were synthesized using the Grignard metathesis method and dicarbonylated by Vilsmeier formylation. Alternating copolymers [C-60-O3AT]n were finally obtained by polycondensation, taking a specific care concerning synthesis conditions in order to optimize polymerization degrees. Nuclear magnetic resonance, infrared spectroscopy, gel permeation chromatography and thermogravimetric analysis were achieved in order to determine the structure of each copolymers. In addition, their functional properties (UV-vis absorption, photoluminescence, and electronic levels) were measured and related to the ascertained average compositions.

  DOI：

  10.1021/ma501788d
• 作为产物：
  描述：

  4,4'-二氨基二苯甲酮 在 吡啶 、 盐酸 、 水 、 potassium carbonate 作用下， 以 四氢呋喃 、 甲醇 、 乙醇 、 甲苯 为溶剂， 反应 52.0h， 生成 4,4'-aminobenzophenone-p-tosylhydrazone
  参考文献：
  名称：

  高效采光有机富勒烯。

  摘要：

  已经制备了二苯基甲基富勒烯-per二酰亚胺二重体和三重体作为光收集器和电子受体，用于制备有效的有机太阳能电池。the单元上燕尾链的存在可提高溶解度，并使其具有完整的特征。[结构：看文字]

  DOI：

  10.1021/ol047451z

文献信息

• Highly Efficient Light-Harvesting Organofullerenes
  作者：Rafael Gómez、José L. Segura、Nazario Martín

  DOI：10.1021/ol047451z

  日期：2005.2.1

  Diphenylmethanofullerene-perylenebisimide dyads and triads have been prepared as light harvesters and electron acceptors for the preparation of efficient organic solar cells. The presence of swallowtail chains on the perylene unit provides enhanced solubility and allows its complete characterization. [Structure: see text]

  已经制备了二苯基甲基富勒烯-per二酰亚胺二重体和三重体作为光收集器和电子受体，用于制备有效的有机太阳能电池。the单元上燕尾链的存在可提高溶解度，并使其具有完整的特征。[结构：看文字]
• Design of a Series of Polythiophenes Containing C₆₀ Groups: Synthesis and Optical and Electrochemical Properties
  作者：Lara Perrin、Mathilde Legros、Régis Mercier

  DOI：10.1021/ma501788d

  日期：2015.1.27

  In order to develop polymers combining both acceptor and donor moieties, a series of alternating copolymers based on C-60 fullerene and oligothiophenes were synthesized. First, a diamino-functionalized fullerene was obtained by a three-step modification of 4,4'-diaminobenzophenone, followed by a BamfordStevens addition on C-60. A series of oligo-3-alkylthiophenes O3AT, with various polymer and alkyl chains lengths, were synthesized using the Grignard metathesis method and dicarbonylated by Vilsmeier formylation. Alternating copolymers [C-60-O3AT]n were finally obtained by polycondensation, taking a specific care concerning synthesis conditions in order to optimize polymerization degrees. Nuclear magnetic resonance, infrared spectroscopy, gel permeation chromatography and thermogravimetric analysis were achieved in order to determine the structure of each copolymers. In addition, their functional properties (UV-vis absorption, photoluminescence, and electronic levels) were measured and related to the ascertained average compositions.