(E)-(S)-4-Methyl-2-tributylstannanyl-hex-2-enoic acid ethyl ester | 144079-77-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: (E)-(S)-4-Methyl-2-tributylstannanyl-hex-2-enoic acid ethyl ester
• 英文别名: ethyl (E,4S)-4-methyl-2-tributylstannylhex-2-enoate
• CAS: 144079-77-6
• 化学式: C₂₁H₄₂O₂Sn
• 分子量: 445.273
• InChiKey: JRGDYDYYCWKHGC-USHJOAKVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.91
• 重原子数：
  24
• 可旋转键数：
  15
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-(S)-4-Methyl-2-tributylstannanyl-hex-2-enoic acid ethyl ester 在 potassium fluoride 、 碘 作用下， 生成 (2E,4S)-2,4-dimethylhex-2-enoic acid
  参考文献：
  名称：

  New and efficient procedures for the synthesis of stereodefined 2-(hetero)aryl and 2-methyl substituted alkyl 2-alkenoates having very high stereoisomeric purity

  摘要：

  Stereodefined 2-(hetero)aryl and 2-methyl substituted alkyl 2-alkenoates of general formula 1 and 2 have been synthesized with a high degree of stereoselectivity as well as in good overall yields starting from alkyl 2-alkynoates, 4.

  DOI：

  10.1016/s0040-4039(00)60119-3

文献信息

• New and efficient procedures for the synthesis of stereodefined 2-(hetero)aryl and 2-methyl substituted alkyl 2-alkenoates having very high stereoisomeric purity
  作者：Renzo Rossi、Adriano Carpita、Paolo Cossi

  DOI：10.1016/s0040-4039(00)60119-3

  日期：1992.7

  Stereodefined 2-(hetero)aryl and 2-methyl substituted alkyl 2-alkenoates of general formula 1 and 2 have been synthesized with a high degree of stereoselectivity as well as in good overall yields starting from alkyl 2-alkynoates, 4.