Process for synthesis of polymer compositions, polymer compositions obtainable by the process, and use of the same
申请人:RohMax Additives GmbH
公开号:US20030060587A1
公开(公告)日:2003-03-27
The present invention relates to a process for synthesis of polymer compositions with reduced catalyst content, wherein ethylenically unsaturated monomers containing less than 0.5 wt % of ethylenically unsaturated monomers with at least one carboxylic group, sulfonic acid group and/or at least one phosphonic acid group relative to the total weight of the ethylenically unsaturated monomers are polymerized by means of initiators containing a transferable group of atoms and of one or more catalysts comprising at least one transition metal in the presence of ligands which can form a coordination compound with the metal catalyst or catalysts and, after the polymerization, the catalyst contained in the polymer is at least partly separated. For this purpose, the polymer composition is filtered, after the polymerization, in the presence of at least one filter aid which contains at least 0.5 wt%, relative to the total weight of the filter aid, of repeating units that contain at least one carboxylic acid group, sulfonic acid group and/or at least one phosphonic acid group.
本发明涉及一种合成聚合物组合物的过程,其具有降低催化剂含量的效果。在该过程中,含有少于0.5重量%的至少含有一个羧基,磺酸基和/或至少一个膦酸基的乙烯基不饱和单体相对于乙烯基不饱和单体的总重量进行聚合,通过含有可转移原子团的引发剂和至少一种过渡金属的催化剂,在与可以形成与金属催化剂或催化剂配合物的配体一起的情况下进行聚合,在聚合之后,聚合物中的催化剂至少部分被分离。为此,在聚合之后,通过至少一种过滤助剂过滤聚合物组合物,该过滤助剂相对于总重量含有至少0.5重量%的重复单元,其中包含至少一个羧酸基,磺酸基和/或至少一个膦酸基。