3-ethynyloxy-phenol | 720679-60-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-ethynyloxy-phenol
• 英文别名: 3-ethynoxyphenol
• CAS: 720679-60-7
• 化学式: C₈H₆O₂
• 分子量: 134.134
• InChiKey: BMLOHZDEYIPBPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-ethynyloxy-phenol 、 2-[2,6-dichloro-4-(3,3-dichloro-allyloxy)-benzyloxy]-ethanol 在 偶氮二甲酸二异丙酯 、 三苯基膦 作用下， 以 甲苯 、 四氢呋喃 为溶剂， 反应 19.42h， 生成 1,3-dichloro-5-(3,3-dichloroallyloxy)-2-[2-(3-ethynyloxy-phenoxy)-ethoxymethyl]-benzene
  参考文献：
  名称：

  [EN] 2,6-DIHALO-4-(3,3-DICHLORO-ALLYLOXY)-BENZYLALCOHOLE DERIVATIVES HAVING INSECTICIDAL AND ACARICIDAL PROPERTIES
  [FR] DERIVES DE 2,6-DIHALO-4-(3,3-DICHLORO-ALLYLOXY-BENZYLALCOOL AUX PROPRIETES INSECTICIDES ET ACARICIDES

  摘要：

  化学式为（I）的化合物，其中：A1是，例如，键或C1-C6烷基桥；A2是，例如，键或C1-C6烷基；A3是，例如，C1-C6烷基；W是，例如，O或S；T是，例如，键，O，NH，NR7，S，SO，S02，-C（=O）-O-或-O-C（=O）-；Q是键，O，NR7，S，SO或S02；Y是O，NR7，S，SO或S02；X1和X2各自独立地是氟、氯、溴或碘；R1是，例如，卤素、CN、硝基、C1-C6烷基或C1-C6卤代烷基；R2和R3是，例如，H、卤素、CN、硝基或C1-C6烷基；R7是，例如，H、C1-C6烷基或C1-C3卤代烷基；m为1或2；E为C1-C6烷基、C1-C6卤代烷基、芳基或杂环基；在适用的情况下，可能的E/Z异构体、E/Z异构体的混合物和/或其互变异构体，均以自由形式或盐形式存在；描述了制备这些化合物的方法和用途；农药组合物中的活性成分选自这些化合物或其可用于农业的盐；制备这些组合物的方法和用途；用这些组合物处理的植物繁殖材料；以及控制害虫的方法。

  公开号：

  WO2004056735A1

文献信息

• A chemoselective cleavable fluorescence turn-ON linker for proteomic studies
  作者：Si Si Liew、Shubo Du、Jingyan Ge、Sijun Pan、Se-Young Jang、Jun-Seok Lee、Shao Q. Yao

  DOI：10.1039/c7cc08235e

  日期：——

  We have developed a trifunctional cleavable fluorescence turn-ON linker for chemoproteomic applications.

  我们已经开发出一种三功能可切割荧光开关连接剂，用于化学蛋白质组学应用。
• 2,6-dihalo-4-(3,3-dichloro-allyloxy)-benzylalcohole derivatives having insecticidal and acaricidal properties
  申请人：Renold Peter

  公开号：US20060063820A1

  公开（公告）日：2006-03-23

  Compounds of formula (I), wherein A 1 is, for example, a bond or a C 1 -C 6 alkylene bridge; A 2 is, for example, a bond or C 1 -C 6 alkylene; A 3 is, for example, C 1 -C 6 alkylene; W is, for example, O or S; T is, for example, a bond, O, NH, NR 7 , S, SO, SO 2 , —C(═O)—O— or —O—C(═O)—; Q is a bond, O, NR 7 , S, SO or SO 2 ; Y is O, NR 7 , S, SO or SO 2 ; X 1 and X 2 are, each independently of the other, fluorine, chlorine, bromine or iodine; R 1 is, for example, halogen, CN, nitro, C 1 -C 6 alkyl or C 1 -C 6 haloalkyl; R 2 and R 3 are, for example, H, halogen, CN, nitro or C 1 -C 6 alkyl; R 7 is, for example, H, C 1 -C 6 alkyl or C 1 -C 3 haloalkyl; m is 1 or 2; and E is C 1 -C 6 alkyl, C 1 -C 6 haloalkyl, aryl or heterocyclyl; and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form; a process for the preparation of and the use of those compounds; pesticidal compositions in which the active ingredient has been selected from those compounds, or an agrochemically usable salt thereof; a process for the preparation of and the use of those compositions; plant propagation material treated with those compositions; and a method of controlling pests are described.

  公式（I）的化合物，其中A1可以是键或C1-C6烷基桥；A2可以是键或C1-C6烷基；A3可以是C1-C6烷基；W可以是O或S；T可以是键，O，NH，NR7，S，SO，SO2，-C（═O）-O-或-O-C（═O）-；Q可以是键，O，NR7，S，SO或SO2；Y可以是O，NR7，S，SO或SO2；X1和X2可以是氟、氯、溴或碘，每个都是独立的；R1可以是卤素、CN、硝基、C1-C6烷基或C1-C6卤代烷基；R2和R3可以是H、卤素、CN、硝基或C1-C6烷基；R7可以是H、C1-C6烷基或C1-C3卤代烷基；m可以是1或2；E可以是C1-C6烷基、C1-C6卤代烷基、芳基或杂环基；如适用，可以是可能的E/Z异构体、E/Z异构体混合物和/或其互变异构体，每种情况下均为自由形式或盐形式；描述了制备这些化合物的过程和使用方法；杀虫剂组合物，其中活性成分已从这些化合物中选择，或其农业化学可用盐；制备这些组合物的方法和使用方法；用这些组合物处理的植物繁殖材料；以及控制害虫的方法。
• 2,6-DIHALO-4-(3,3-DICHLORO-ALLYLOXY)-BENZYLALCOHOLE DERIVATIVES HAVING INSECTICIDAL AND ACARICIDAL PROPERTIES
  申请人：Syngenta Participations AG

  公开号：EP1581470A1

  公开（公告）日：2005-10-05
• MEMBRANES AND METHOD FOR THE PRODUCTION THEREOF
  申请人：LEIBNIZ-INSTITUT FUER POLYMERFORSCHUNG DRESDEN E.V

  公开号：US20170036173A1

  公开（公告）日：2017-02-09

  The invention concerns the field of polymer chemistry and relates to membranes, such as those used as membranes for the preparation of aqueous solutions by means of reverse osmosis or microfiltration, ultrafiltration or nanofiltration, for example. The object of the present invention is the specification of membranes that exhibit a reduced fouling tendency with equally suitable or improved filtration properties, as well as the specification of a simple and cost-effective method for the production thereof. The object is attained with membranes comprising a substrate on which a porous supporting layer is arranged, on which supporting layer a separation-active layer is arranged, and on which separation-active layer a cover layer is also arranged, wherein the material of the separation-active layer comprises functional groups which primarily have carbon-carbon triple bonds and/or carbon-nitrogen triple bonds, and wherein the material of the cover layer has functional groups which are primarily at least azide groups, and the functional groups having at least carbon-carbon triple bonds and/or carbon-nitrogen triple bonds are chemically coupled covalently with the azide groups.
• [EN] 2,6-DIHALO-4-(3,3-DICHLORO-ALLYLOXY)-BENZYLALCOHOLE DERIVATIVES HAVING INSECTICIDAL AND ACARICIDAL PROPERTIES<br/>[FR] DERIVES DE 2,6-DIHALO-4-(3,3-DICHLORO-ALLYLOXY-BENZYLALCOOL AUX PROPRIETES INSECTICIDES ET ACARICIDES
  申请人：SYNGENTA PARTICIPATIONS AG

  公开号：WO2004056735A1

  公开（公告）日：2004-07-08

  Compounds of formula (I), wherein: A1 is, for example, a bond or a C1-C6alkylene bridge; A2 is, for example, a bond or C1-C6alkylene; A3 is, for example, C1-C6alkylene; W is, for example, O or S; T is, for example, a bond, O, NH, NR7, S, SO, S02, -C(=O)-O- or -O-C(=O)-; Q is a bond, O, NR7, S, SO or S02; Y is O, NR7, S, SO or S02; X1 and X2 are, each independently of the other, fluorine, chlorine, bromine or iodine; R1 is, for example, halogen, CN, nitro, C1-C6alkyl or C1-C6haloalkyl; R2 and R3 are, for example, H, halogen, CN, nitro or C1-C6alkyl; R7 is, for example, H, C1-C6alkyl or C1-C3haloalkyl; m is 1 or 2; and E is C1-C6alkyl, C1-C6haloalkyl, aryl or heterocyclyl; and, where applicable, possible E/Z isomers, mixtures of E/Z isomers and/or tautomers thereof, in each case in free form or in salt form; a process for the preparation of and the use of those compounds; pesticidal compositions in which the active ingredient has been selected from those compounds, or an agrochemically usable salt thereof; a process for the preparation of and the use of those compositions; plant propagation material treated with those compositions; and a method of controlling pests are described.

  化学式为（I）的化合物，其中：A1是，例如，键或C1-C6烷基桥；A2是，例如，键或C1-C6烷基；A3是，例如，C1-C6烷基；W是，例如，O或S；T是，例如，键，O，NH，NR7，S，SO，S02，-C（=O）-O-或-O-C（=O）-；Q是键，O，NR7，S，SO或S02；Y是O，NR7，S，SO或S02；X1和X2各自独立地是氟、氯、溴或碘；R1是，例如，卤素、CN、硝基、C1-C6烷基或C1-C6卤代烷基；R2和R3是，例如，H、卤素、CN、硝基或C1-C6烷基；R7是，例如，H、C1-C6烷基或C1-C3卤代烷基；m为1或2；E为C1-C6烷基、C1-C6卤代烷基、芳基或杂环基；在适用的情况下，可能的E/Z异构体、E/Z异构体的混合物和/或其互变异构体，均以自由形式或盐形式存在；描述了制备这些化合物的方法和用途；农药组合物中的活性成分选自这些化合物或其可用于农业的盐；制备这些组合物的方法和用途；用这些组合物处理的植物繁殖材料；以及控制害虫的方法。