Di(4-bromphenyl)jodonium | 46449-54-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Di(4-bromphenyl)jodonium
• 英文别名: Bis(4-bromphenyl)jodonium；Bis(4-bromophenyl)iodanium
• CAS: 46449-54-1
• 化学式: C₁₂H₈Br₂I
• 分子量: 438.908
• InChiKey: RKJMYAKRQZRZCW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Di(4-bromphenyl)jodonium 、 Norharman-2-oxide 在 potassium carbonate 作用下， 以 1,2-二氯乙烷 、 甲醇 为溶剂， 反应 49.0h， 以87%的产率得到4-bromo-2-(9H-pyrido[3,4-b]indol-2-ium-2-yl)phenolate
  参考文献：
  名称：

  吡啶N-氧化物和N-氨基甲酸酯通过1,3-基团重排直接取代邻二氮杂鎓盐

  摘要：

  配对：标题反应导致一系列邻吡啶吡啶酚（1）和苯胺（2）。实验和计算研究表明，关键步骤涉及均相裂解生成自由基对，然后进行溶剂-笼重组以生成产物。

  DOI：

  10.1002/anie.201303347

文献信息

• [EN] DENTAL COMPOSITION COMPRISING A PARTICULATE CARRIER SUPPORTING A COINITIATOR<br/>[FR] COMPOSITION DENTAIRE COMPRENANT UN SUPPORT PARTICULAIRE CONTENANT UN CO-INITIATEUR
  申请人：DENTSPLY DETREY GMBH

  公开号：WO2019043056A1

  公开（公告）日：2019-03-07

  The present invention relates to a dental composition comprising a photoinitiator system comprising a particulate carrier supporting a coinitiator covalently bonded to the surface of the carrier. Furthermore, the present invention relates to a use of the particulate carrier in a dental composition. The particulate carrier displays multiple covalently bonded tertiary amino groups and/or tertiary phosphine groups on the surface, for crosslinking monomers, oligomers and/or polymers having one or more polymerizable double bonds.

  本发明涉及一种牙科组合物，其包括一种光引发剂系统，该系统包括一种颗粒载体，支持着与载体表面共价结合的辅助引发剂。此外，本发明涉及将该颗粒载体用于牙科组合物的用途。该颗粒载体在表面显示多个共价结合的三级胺基团和/或三级膦基团，用于交联具有一个或多个可聚合双键的单体、寡聚物和/或聚合物。
• [EN] DENTAL COMPOSITION<br/>[FR] COMPOSITION DENTAIRE
  申请人：DENTSPLY DETREY GMBH

  公开号：WO2017060459A1

  公开（公告）日：2017-04-13

  The present invention relates to a dental composition comprising a specific polymerization initiator system comprising a compound having an acylsilyl- or acylgermanyl-group. The present invention also relates the use of the compound having an acylsilyl- or acylgermanylgroup for the preparation of a dental composition.

  本发明涉及一种牙科组合物，包括一种特定的聚合引发剂系统，该系统包括具有酰基硅基或酰基锗基的化合物。本发明还涉及使用具有酰基硅基或酰基锗基的化合物制备牙科组合物。
• [EN] PHOTOCURABLE DENTAL COMPOSITION<br/>[FR] COMPOSITION DENTAIRE PHOTODURCISSABLE
  申请人：DENTSPLY DETREY GMBH

  公开号：WO2019072787A1

  公开（公告）日：2019-04-18

  The present invention relates to a photocurable dental composition comprising a specific polymerization initiator system containing the combination of a photoinitiator compound and a coinitiator compound being a sulfinate compound or a sulfonate compound. The present invention also relates to the use of this polymerization initiator system in a photocurable dental composition.

  本发明涉及一种光固化牙科组合物，包括一种特定的聚合引发剂体系，其中包含光引发剂化合物和共同引发剂化合物的组合，后者是磺酸盐化合物或亚磺酸盐化合物。本发明还涉及将该聚合引发剂体系用于光固化牙科组合物的用途。
• Process for preparing diaryls
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0119065A1

  公开（公告）日：1984-09-19

  A process for preparing a diaryl or a mixture of diaryls represented by any or a combination of the following formulae (II), (III), and (IV), characterized in that a diaryliodonium salt represented by the following formula (1) is reacted in a solvent in the presence of a transition metal catalyst and a reducing metal at a temperature in the range of room temperature to 100°C: wherein Ar1 and Ar2, which may be alike or different, are each an aryl group which may have a substituent group or groups and X⊖ is a counter ion which is inert to said reaction.

  一种制备由下式(II)、(III)和(IV)中任何一种或其组合代表的二芳基或二芳基混合物的工艺，其特征在于由下式(1)代表的二芳基碘鎓盐在溶剂中，在过渡金属催化剂和还原金属存在下，于室温至100℃范围内进行反应： 其中 Ar1 和 Ar2（可以相同或不同）各自为芳基，可带有一个或多个取代基，X⊖ 为对所述反应惰性的反离子。
• Process for arylating unsaturated compounds
  申请人：NIPPON PETROCHEMICALS COMPANY, LIMITED

  公开号：EP0129956A1

  公开（公告）日：1985-01-02

  A process for converting an aromatic compound to prepare an iodoarene, Ar-1, and an aryl compound in which an unsaturated compound is bonded directly to an aryl group, Ar, which process comprises reacting a diaryliodonium salt represented by general formula (I) wherein Ar is an aryl group which may be substituted and two Ar's are identical and X⊖ is a counter ion inert to the reaction with the unsaturated compound in a solvent in the presence of a transition metal catalyst and a base or a reducing metal, said reaction being carried out at a temperature not higher than 80°C and/or by using at least one of the base, the reducing metal and the unsaturated compound in an amount not more than 1.5 times the stoichiometric amount, then separating the iodoarene Ar-I thus formed from the reaction mixture, subsequently coupling said iodoarene thus separated with an aromatic compound, ArH. in an oxidizing atmosphere in the presence of X⊖'[ or an anion ion-exchangeable with X0, if needed ion-exchanging the anion with X⊖, to form the diaryl iodonium salt of the above general formula (I), and recycling said diaryl iodonium salt thus formed in said reaction.

  一种将芳香族化合物转化以制备碘代芳烃 Ar-1 和芳基化合物的工艺，其中不饱和化合物 直接与芳基 Ar 键合，该工艺包括使通式(I)代表的二芳基碘鎓盐反应 其中 Ar 是可被取代的芳基，且两个 Ar 相同，X⊖ 是与不饱和化合物在溶剂中在过渡金属催化剂和碱或还原金属存在下反应的惰性反离子，所述反应在不高于 80°C 的温度下和/或通过使用碱、还原金属和不饱和化合物中的至少一种，其用量不超过 1.5倍，然后从反应混合物中分离出由此形成的碘芳烃Ar-I，随后在氧化气氛中，在X⊖'[或可与X0离子交换的阴离子（如需要可与X⊖离子交换）的存在下，将由此分离出的所述碘芳烃与芳香族化合物ArH.偶联，形成上述通式(I)的二芳基碘鎓盐，并回收在所述反应中由此形成的所述二芳基碘鎓盐。