4-[Bis-(4-butyl-phenyl)-amino]-2-[5-(tert-butyl-dimethyl-silanyloxy)-pentyloxy]-benzaldehyde | 230623-58-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-[Bis-(4-butyl-phenyl)-amino]-2-[5-(tert-butyl-dimethyl-silanyloxy)-pentyloxy]-benzaldehyde
• 英文别名: 4-(4-butyl-N-(4-butylphenyl)anilino)-2-[5-[tert-butyl(dimethyl)silyl]oxypentoxy]benzaldehyde
• CAS: 230623-58-2
• 化学式: C₃₈H₅₅NO₃Si
• 分子量: 601.945
• InChiKey: NGNISZVGOORQBW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.22
• 重原子数：
  43
• 可旋转键数：
  19
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  4-[Bis-(4-butyl-phenyl)-amino]-2-[5-(tert-butyl-dimethyl-silanyloxy)-pentyloxy]-benzaldehyde 在 正丁基锂 、 sodium ethanolate 作用下， 以 乙醇 为溶剂， 反应 9.75h， 生成
  参考文献：
  名称：

  Synthesis of Functionalized Organic Second-Order Nonlinear Optical Chromophores for Electrooptic Applications

  摘要：

  The design and syntheses of functionalized second-order nonlinear optical chromophores, suitable for covalent incorporation into functionalized high-performance polymers, are described. The chromophores with hydroxy alkyl functionality have diarylamino groups as the donor moiety and a styryl thiophene moiety as the conjugated bridge. The triarylamine parts of the molecules were synthesized using palladium-catalyzed C-N bond forming reactions. The conjugated bridge was assembled using the Wittig reaction. The acceptor groups were installed in the last steps of the syntheses.

  DOI：

  10.1021/jo981707v
• 作为产物：
  描述：

  间氨基苯甲醚 在 1,1'-双(二苯基膦)二茂铁 、 tris(dibenzylideneacetone)dipalladium (0) 、 三溴化硼 、 sodium t-butanolate 作用下， 以 二氯甲烷 为溶剂， 反应 27.17h， 生成 4-[Bis-(4-butyl-phenyl)-amino]-2-[5-(tert-butyl-dimethyl-silanyloxy)-pentyloxy]-benzaldehyde
  参考文献：
  名称：

  Synthesis of Functionalized Organic Second-Order Nonlinear Optical Chromophores for Electrooptic Applications

  摘要：

  The design and syntheses of functionalized second-order nonlinear optical chromophores, suitable for covalent incorporation into functionalized high-performance polymers, are described. The chromophores with hydroxy alkyl functionality have diarylamino groups as the donor moiety and a styryl thiophene moiety as the conjugated bridge. The triarylamine parts of the molecules were synthesized using palladium-catalyzed C-N bond forming reactions. The conjugated bridge was assembled using the Wittig reaction. The acceptor groups were installed in the last steps of the syntheses.

  DOI：

  10.1021/jo981707v

文献信息

• Synthesis of Functionalized Organic Second-Order Nonlinear Optical Chromophores for Electrooptic Applications
  作者：S. Thayumanavan、Jeffrey Mendez、Seth R. Marder

  DOI：10.1021/jo981707v

  日期：1999.6.1

  The design and syntheses of functionalized second-order nonlinear optical chromophores, suitable for covalent incorporation into functionalized high-performance polymers, are described. The chromophores with hydroxy alkyl functionality have diarylamino groups as the donor moiety and a styryl thiophene moiety as the conjugated bridge. The triarylamine parts of the molecules were synthesized using palladium-catalyzed C-N bond forming reactions. The conjugated bridge was assembled using the Wittig reaction. The acceptor groups were installed in the last steps of the syntheses.