2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy)phenyl)ethyl)phenol | 1264748-97-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy)phenyl)ethyl)phenol
• 英文别名: 2,4-Ditert-butyl-6-[1-[3,5-ditert-butyl-2-[2-(2-methoxyethoxy)ethoxy]phenyl]ethyl]phenol；2,4-ditert-butyl-6-[1-[3,5-ditert-butyl-2-[2-(2-methoxyethoxy)ethoxy]phenyl]ethyl]phenol
• CAS: 1264748-97-1
• 化学式: C₃₅H₅₆O₄
• 分子量: 540.827
• InChiKey: NDQLKNVYNMISRR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.2
• 重原子数：
  39
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.66
• 拓扑面积：
  47.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy)phenyl)ethyl)phenol 在 sodium 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以91%的产率得到
  参考文献：
  名称：

  Synthesis, characterization of sodium and potassium complexes and the application in ring-opening polymerization of L-lactide

  摘要：

  A novel sterically bulky phenol (2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy) phenyl)ethyl)phenol)(HL) and corresponding dimeric sodium and potassium complexes [ML](2) (1: M = Na, 2: M = K) have been prepared and structurally characterized. Experimental results showed that complexes 1 and 2 can efficiently initiate the ring-opening polymerization of lactide in a controlled fashion, yielding polymers with expected molecular weight and low polydispersity indexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.09.021
• 作为产物：
  描述：

  2-(2-甲氧基乙氧基)乙基4-甲基苯磺酸负离子 、 2,2′-亚乙基双(4,6-二叔丁基酚) 以 N,N-二甲基甲酰胺 为溶剂， 反应 12.0h， 以89%的产率得到2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy)phenyl)ethyl)phenol
  参考文献：
  名称：

  Synthesis, characterization of sodium and potassium complexes and the application in ring-opening polymerization of L-lactide

  摘要：

  A novel sterically bulky phenol (2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy) phenyl)ethyl)phenol)(HL) and corresponding dimeric sodium and potassium complexes [ML](2) (1: M = Na, 2: M = K) have been prepared and structurally characterized. Experimental results showed that complexes 1 and 2 can efficiently initiate the ring-opening polymerization of lactide in a controlled fashion, yielding polymers with expected molecular weight and low polydispersity indexes. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.09.021

文献信息

• Synthesis, characterization of sodium and potassium complexes and the application in ring-opening polymerization of L-lactide
  作者：Longhai Chen、Lei Jia、Feixiang Cheng、Lei Wang、Chu-chieh Lin、Jincai Wu、Ning Tang

  DOI：10.1016/j.inoche.2010.09.021

  日期：2011.1

  A novel sterically bulky phenol (2,4-di-tert-butyl-6-(1-(3,5-di-tert-butyl-2-(2-(2-methoxyethoxy)ethoxy) phenyl)ethyl)phenol)(HL) and corresponding dimeric sodium and potassium complexes [ML](2) (1: M = Na, 2: M = K) have been prepared and structurally characterized. Experimental results showed that complexes 1 and 2 can efficiently initiate the ring-opening polymerization of lactide in a controlled fashion, yielding polymers with expected molecular weight and low polydispersity indexes. (C) 2010 Elsevier B.V. All rights reserved.