| 143880-77-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 143880-77-7
• 化学式: C₁₁H₁₈Ge
• 分子量: 222.854
• InChiKey: LAIKEHQDYYEMKS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.31
• 重原子数：
  12.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  (2,4,6-trimethylphenyl)GeH3 在 叔丁基锂 、 碘甲烷 作用下， 以 四氢呋喃 为溶剂， 以35%的产率得到
  参考文献：
  名称：

  Nouveaux aryldihydrogermyllithium

  摘要：

  The new aryldihydrogermyllithium complexes RH2GeLi (R = Ph, Mes) are prepared, in good yields, by metallation of the parent trihydrogermane with t-butyllithium in THF. They are characterized by alkylation reactions with MeI. Some germylation reactions are reported: they lead to the formation of new functional aryldihydrogermanes and aryldigermanes by a nucleophilic substitution. These aryldihydrogermyllithium complexes react also with acyl chlorides RCOCl (R = Ph, Mes) to give new diacyl- and triacyl-germanes. These easily add to the carbonyl group of aromatic aldehydes, thereby giving the corresponding alpha-germyl alcohols.

  DOI：

  10.1016/0022-328x(92)80129-l

文献信息

• The photolysis of Si,Si-di-<i>tert</i>-butyltetramesitylsiladigermirane in the presence of methylmagnesium iodide
  作者：Mini S Samuel、Kim M Baines、Donald W Hughes

  DOI：10.1139/v00-058

  日期：2000.11.1

  The photolysis of Si,Si-di-tert-butyltetramesitylsiladigermirane in the presence of methylmagnesium iodide at 15°C has been investigated. Five products were isolated and identified from the complex product mixture: mesityldimethylgermane, dimesitylmethylgermane, (di-tert-butylmethylsilyl)mesitylmethylgermane, meta-(di-tert-butylmethylsilyl)toluene, and para-(di-tert-butylmethylsilyl)toluene. The characterization

  已经研究了在甲基碘化镁存在下在 15°C 下 Si,Si-二叔丁基四甲基硅二锗烷的光解。从复杂的产物混合物中分离并鉴定了五种产物：均三甲苯基二甲基锗烷、二甲苯基甲基锗烷、（二叔丁基甲基甲硅烷基）三甲苯基甲基锗烷、间（二叔丁基甲基甲硅烷基）甲苯和对（二叔丁基甲基甲硅烷基）甲苯。将讨论这些化合物的表征及其形成机制。关键词：锗硅烯，格氏试剂，锗基镁化合物。
• Nouveaux aryldihydrogermyllithium
  作者：A. Castel、P. Rivière、J. Satgé、D. Desor

  DOI：10.1016/0022-328x(92)80129-l

  日期：1992.7

  The new aryldihydrogermyllithium complexes RH2GeLi (R = Ph, Mes) are prepared, in good yields, by metallation of the parent trihydrogermane with t-butyllithium in THF. They are characterized by alkylation reactions with MeI. Some germylation reactions are reported: they lead to the formation of new functional aryldihydrogermanes and aryldigermanes by a nucleophilic substitution. These aryldihydrogermyllithium complexes react also with acyl chlorides RCOCl (R = Ph, Mes) to give new diacyl- and triacyl-germanes. These easily add to the carbonyl group of aromatic aldehydes, thereby giving the corresponding alpha-germyl alcohols.