4-Methyl-6-bromhexansaure | 100959-00-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 4-Methyl-6-bromhexansaure
• 英文别名: 6-bromo-4-methyl-hexanoic acid；6-Brom-4-methyl-hexansaeure；6-Bromo-4-methylhexanoic acid；6-bromo-4-methylhexanoic acid
• CAS: 100959-00-0
• 化学式: C₇H₁₃BrO₂
• 分子量: 209.083
• InChiKey: OFOUJAKIHDGMFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-Methyl-6-bromhexansaure 在 KAuBr₂ 、 alkaline Na₂SO₃ 、 水 作用下， 生成 6-mercapto-4-methyl-hexanoic acid
  参考文献：
  名称：

  ι-Aurothio Fatty Acids and their Salts

  摘要：

  DOI：

  10.1021/ja01194a029
• 作为产物：
  描述：

  4-甲基环己酮 在 双氧水 作用下， 生成 4-Methyl-6-bromhexansaure
  参考文献：
  名称：

  Minisci; Portolani, Gazzetta Chimica Italiana, 1959, vol. 89, p. 1922,1937

  摘要：

  DOI：

文献信息

• Luminescent compositions
  申请人：Kelly Malcolm Stephen

  公开号：US20050253112A1

  公开（公告）日：2005-11-17

  A composition capable of emitting circularly polarised light comprises a medium including a chiral, helical liquid crystalline phase with a substantially fixed, temperature independent helical pitch. The liquid crystalline phase is comprised of calamatic liquid crystal molecules having a luminescent moiety and the composition is such that excitation of the luminescent moiety causes the medium to emit light in the bandwidth of selective reflection of the liquid crystalline phase. To achieve the substantially temperature independent helical pitch, the chiral helical liquid crystalline phase may be in the form of a glass or a polymerised network. The composition may be used to produce a light emitting device, e.g. and OLED.

  一种能够发射圆偏光的组合物，包括一种介质，其中包含一种手性、螺旋液晶相，其具有实质上固定的、温度独立的螺旋步距。该液晶相由具有发光基团的灾变型液晶分子组成，组合物的构成使得激发发光基团会导致介质在液晶相选择性反射的频带内发射光。为了实现实质上温度独立的螺旋步距，手性螺旋液晶相可以以玻璃或聚合网络形式存在。该组合物可以用于制造发光装置，例如OLED。
• LUMINESCENT COMPOSITIONS
  申请人：The University of Hull

  公开号：EP1523533B1

  公开（公告）日：2007-08-15
• [EN] LUMINESCENT COMPOSITIONS<br/>[FR] COMPOSITIONS LUMINESCENTES
  申请人：UNIV HULL

  公开号：WO2004003108A1

  公开（公告）日：2004-01-08

  A composition capable of emitting circularly polarised light comprises a medium including a chiral, helical liquid crystalline phase with a substantially fixed, temperature independent helical pitch. The liquid crystalline phase is comprised of calamatic liquid crystal molecules having a luminescent moiety and the composition is such that excitation of the luminescent moiety causes the medium to emit light in the bandwidth of selective reflection of the liquid crystalline phase. To achieve the substantially temperature independent helical pitch, the chiral helical liquid crystalline phase may be in the form of a glass or a polymerised network. The composition may be used to produce a light emitting device, e.g. and OLED.
• Minisci; Portolani, Gazzetta Chimica Italiana, 1959, vol. 89, p. 1922,1937
  作者：Minisci、Portolani

  DOI：——

  日期：——
• ι-Aurothio Fatty Acids and their Salts
  作者：E. E. Moore、R. T. Rapala

  DOI：10.1021/ja01194a029

  日期：1947.2