(Z)-7,7,8,8,9,9,10,10,10-nonafluoro-5-decenyl acetate | 137648-84-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (Z)-7,7,8,8,9,9,10,10,10-nonafluoro-5-decenyl acetate
• 英文别名: (Z)-7,7,8,8,9,9,10,10,10-Nonafluoro-5-decen-1-ol acetate；[(Z)-7,7,8,8,9,9,10,10,10-nonafluorodec-5-enyl] acetate
• CAS: 137648-84-1
• 化学式: C₁₂H₁₃F₉O₂
• 分子量: 360.22
• InChiKey: VXZVGXQFUZRFFK-XQRVVYSFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  23
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  (E)-5-iodo-7,7,8,8,9,9,10,10,10-nonafluoro-5-decen-1-ol 在 吡啶 、 甲醇 、 正丁基锂 、 N-[(2,4-二氯苯氧基)-甲氧基硫代膦酰]丙-2-胺 作用下， 反应 1.5h， 生成 (Z)-7,7,8,8,9,9,10,10,10-nonafluoro-5-decenyl acetate
  参考文献：
  名称：

  Synthesis of partially fluorinated analogs of (Z)-5-decenyl acetate: probes for hydrophobic interaction in pheromone reception

  摘要：

  Selective regiochemical introduction of fluorines into methyl and methylene positions of (Z)-5-decenyl acetate provides analogues to probe the hydrophobicity requirements of the pheromone receptor site in the turnip moth, Agrotis segetum. Perfluorobutyl-, difluoromethylene-, trifluoromethyl-, and tetrafluoroethylene-containing analogues have been synthesized and chemically characterized.

  DOI：

  10.1021/jo00027a025

文献信息

• Synthesis of partially fluorinated analogs of (Z)-5-decenyl acetate: probes for hydrophobic interaction in pheromone reception
  作者：Wei Chuan Sun、Chi Shing Ng、Glenn D. Prestwich

  DOI：10.1021/jo00027a025

  日期：1992.1

  Selective regiochemical introduction of fluorines into methyl and methylene positions of (Z)-5-decenyl acetate provides analogues to probe the hydrophobicity requirements of the pheromone receptor site in the turnip moth, Agrotis segetum. Perfluorobutyl-, difluoromethylene-, trifluoromethyl-, and tetrafluoroethylene-containing analogues have been synthesized and chemically characterized.