Benzotriazol-1-ylmethyl-diisobutyl-amine | 137273-38-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: Benzotriazol-1-ylmethyl-diisobutyl-amine
• 英文别名: (1H-1,2,3-Benzotriazol-1-ylmethyl)bis(2-methylpropyl)amine；N-(benzotriazol-1-ylmethyl)-2-methyl-N-(2-methylpropyl)propan-1-amine
• CAS: 137273-38-2
• 化学式: C₁₅H₂₄N₄
• 分子量: 260.382
• InChiKey: CAIBGENFUYAVQL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  34
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Benzotriazol-1-ylmethyl-diisobutyl-amine 、 3-溴丙烯 在 bismuth(III) chloride 、 氢化铝 作用下， 以 四氢呋喃 、 水 为溶剂， 以85%的产率得到N-but-3-enyl-2-methyl-N-(2-methylpropyl)propan-1-amine
  参考文献：
  名称：

  Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

  摘要：

  In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20-degrees-C in THF-water to give the corresponding homoalkylated amines in high yields.

  DOI：

  10.1016/s0040-4039(00)92139-7
• 作为产物：
  描述：

  二异丁胺 、 1H-苯并三唑-1-甲醇 生成 Benzotriazol-1-ylmethyl-diisobutyl-amine
  参考文献：
  名称：

  Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media

  摘要：

  In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20-degrees-C in THF-water to give the corresponding homoalkylated amines in high yields.

  DOI：

  10.1016/s0040-4039(00)92139-7

文献信息

• Lubricating Oil Composition
  申请人：Kouno Kunihiro

  公开号：US20190300810A1

  公开（公告）日：2019-10-03

  The invention relates to reducing friction coefficient in automotive lubricating oil, in particular although not exclusively at lower temperature by combining molybdenum dithiocarbamate additives with benzotriazole derivative corrosion inhibitors.
• Water-tolerant unstabilized carbanion equivalents: Bismuth(III) chloride-aluminum promoted alkylations of immonium cations to amines in aqueous Media
  作者：Alan.R. Katritzky、Navayath Shobana、Philip A. Harris

  DOI：10.1016/s0040-4039(00)92139-7

  日期：1991.1

  In the presence of bismuth(III) chloride-metallic aluminum, alkyl as well as allyl halides react with N-(alkylamino)benzotriazoles at 20-degrees-C in THF-water to give the corresponding homoalkylated amines in high yields.