Acrylsaeure-<2-(butyl-amino)-aethylester> | 7709-09-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Acrylsaeure-<2-(butyl-amino)-aethylester>
• 英文别名: 2-(Butylamino)ethyl prop-2-enoate
• CAS: 7709-09-3
• 化学式: C₉H₁₇NO₂
• 分子量: 171.239
• InChiKey: GSQIVVSEVORPJF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  38.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2-丁氨基乙醇 、 丙烯酰氯 在 盐酸 作用下， 以 氯仿 为溶剂， 生成 Acrylsaeure-<2-(butyl-amino)-aethylester>
  参考文献：
  名称：

  Korshunov,M.A. et al., Journal of Organic Chemistry USSR (English Translation), 1969, vol. 5, # 2, p. 244 - 251

  摘要：

  DOI：

文献信息

• IONIC COMPOUND, COMPOSITION, CURED MATERIAL, HYDROGEL AND OPHTHALMIC LENS
  申请人：Satake Kohsuke

  公开号：US20130202551A1

  公开（公告）日：2013-08-08

  An ionic compound capable of providing a cured material having superior antibacterial property and oxygen permeability, and a composition containing the ionic compound, and a cured material, a hydro gel and an ophthalmic lens which have long-term sustainable antibacterial property and superior oxygen permeability. The ionic compound is represented by the following formula (1): In formula (1), P represents a polymerizable functional group. Q + represents a cationic group: Z represents an n-valent siloxanyl group in which the total atomic weight of a group of constituent atoms is no less than 70 and no greater than 1,000; X m− represents an m-valent anion; and n is an integer of 1 to 10, where provided that n is no less than 2, a plurality of P3 and Q + 3 are each independently as defined above.

  一种离子化合物，能够提供具有优越抗菌性能和氧透性的固化材料，以及含有该离子化合物的组合物，以及具有长期可持续抗菌性能和优越氧透性的固化材料、水凝胶和眼镜片。该离子化合物由以下式（1）表示： 在式（1）中，P代表可聚合的功能基团。Q + 代表阳离子基团：Z代表一个n价硅氧烷基团，其中构成原子的总原子量不小于70且不大于1,000；X m− 代表m价阴离子；n为1至10的整数，其中n不小于2时，多个P3和Q + 3分别独立定义如上所述。
• Membranes
  申请人：Antheunis Harro

  公开号：US20120024697A1

  公开（公告）日：2012-02-02

  Process for manufacturing a composite membrane comprising a porous support and a polymeric separation layer having acidic or basic groups comprising the steps of: (i) applying a composition to a porous support; and (ii) curing the composition to form the polymeric separation layer thereon; wherein the composition comprises the components (a) a compound having one ethylenically unsaturated group; and (b) a crosslinking agent having an acrylamide group; and wherein the curing is achieved by irradiating the composition for less than 30 seconds. The membranes are useful in reverse electrodialysis e.g. for generating blue energy and have good resistance to deterioration, even under hot and high pH conditions.

  制造复合膜的工艺包括以下步骤：(i)将一种组合物应用于多孔支撑体上；(ii)使组合物固化，形成聚合物分离层；其中，所述组合物包括组分(a)具有一个乙烯基不饱和基团的化合物；和组分(b)具有丙烯酰胺基团的交联剂；所述固化是通过照射该组合物不超过30秒实现的。该膜在反向电渗析中非常有用，例如用于产生蓝色能源，并且即使在高温和高pH条件下也具有很好的耐久性。
• Water-absorbent starch copolymerisates and method for their preparation.
  申请人：A.E. STALEY MANUFACTURING COMPANY

  公开号：EP0000247A1

  公开（公告）日：1979-01-10

  O Water-absorbent, starch copolymerisates which comprise a non-linear lattice of starch chains linked together by polymeric linkages represented by the formula wherein Starch represents a starch chain of D-glucose units, Z represents an organo group which links the group to the carbon atom of the starch chain by a sulphur or an oxygen atom, R is hydrogen or a monovalent organic radical, M represents a plurality of copolymerised ethylenically unsaturated monomers with "p" representing the number of copolymerised monomeric units in the linkage, (W) is a water-attractant group linked to the polymeric linkage and "n" represents the number of (W) moieties contained within the polymeric linkage of the copolymerised monomers with the number of (W) moieties being sufficient to impart water-absorbency properties to the copolymerisate. The water-absorbent starch copolymerisate may be easily prepared into a desired configuration for a particular end-use or combined with other substrates or carriers. The unpolymerised starch and monomers or precursors thereof may be applied or incorporated into a suitable carrier.or substrate and copolymerised in situ to provide a composite article of unitary construction with the water-absorbent starch copolymerisate permanently bonded or affixed thereto.

  O 具有吸水性的淀粉共聚物，它由通过聚合物链节连接在一起的淀粉链的非线性晶格组成，聚合物链节由以下式子表示 其中，淀粉代表由 D-葡萄糖单元组成的淀粉链，Z 代表有机基团，它将有机基团与淀粉链的碳原子连接在一起。 R 是氢或一价有机基，M 代表多种共聚乙烯不饱和单体，"p "代表连接中共聚单体单元的数量、(W）是与聚合连接相连的吸水基团，"n "代表共聚单体的聚合连接中包含的（W）分子的数量，（W）分子的数量足以使共聚物具有吸水性能。吸水性淀粉共聚物可以很容易地制备成特定最终用途所需的结构，或与其他基质或载体结合。可将未聚合的淀粉及其单体或前体涂抹或掺入适当的载体或基质中，并在原位进行共聚，以提供具有吸水性淀粉共聚物永久粘合或附着于其上的整体结构的复合物品。
• Stabilized resin solutions
  申请人：Takeda Chemical Industries, Ltd.

  公开号：EP0223217A2

  公开（公告）日：1987-05-27

  A stabilized solution of a copolymer composed of an aminoalkyl acrylate unit or aminoalkyl methacrylate unit and an ethylenically unsaturated monomer unit, which is prepared by dissolving the copolymer in a mixed solvent containing a ketone solvent in a ratio of about 20 to 80wt.% to the total solvent weight. The stabilized solution possesses highly improved storage stability, thus standing long-term storage; it works well for paints, adhesives, primers, etc. Its adhesive property to various substances is further improved by adding a coupling agent. In addition, a paint film excellent in adhesion, water resistance, chemical resistance, and weatherproofness can be obtained by using both the stabilized solution of the base copolymer and either a compound having at least 2 acryloyl groups in each molecule, a blocked polyisocyanate compound, or an epoxy compound as a hardener.

  一种由丙烯酸氨基烷基酯单元或甲基丙烯酸氨基烷基酯单元和乙烯基不饱和单体单元组成的共聚物的稳定溶液，其制备方法是将共聚物溶解在含有酮类溶剂的混合溶剂中，混合溶剂的重量占溶剂总重量的比例约为 20 至 80%。稳定后的溶液具有更高的储存稳定性，因此可以长期储存；在油漆、粘合剂、底漆等方面也有很好的效果。通过添加偶联剂，还可进一步改善其与各种物质的粘合性。此外，通过同时使用基础共聚物的稳定溶液和每个分子中至少含有 2 个丙烯酰基的化合物、嵌段多异氰酸酯化合物或环氧化合物作为固化剂，可以获得附着力、耐水性、耐化学性和耐候性都很好的漆膜。
• Ethylene copolymers as sorbers of metallic ions from solutions
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0340975A1

  公开（公告）日：1989-11-08

  A copolymer is prepared, by high pressure radical polymerisation, of, by wt, 40-95 % of ethylene, 5 -60 % of at least one aminoalkyl acrylate of the formula: where R, is H or methyl, R2 and R3 each are C1 -4. alkyl and n is 1, 2, 3 or 4, and optionally also up to 20 % of another copolymerizable monomer, the copolymer having a number average molecular weight of 5000 to 50,000. The copolymer is molded to pellets, beads, sheets, mats, cloth or cartridges and used as a filter to sorb metal ions, other than Fe or Co, from waste industrial aqueous solution containing metal ions, e.g. ions of Pd, Cr or U, the solution being adjusted to appropriate pH. The copolymer can be washed with water of different pH to recover the metal; or it can be burnt and the metal recovered from the ash.

  通过高压自由基聚合法制备一种共聚物，按重量百分比计，由 40-95% 的乙烯、5-60% 的至少一种式中的氨基烷基丙烯酸酯组成： 式中 R 为 H 或甲基，R2 和 R3 分别为 C1 -4. 烷基，n 为 1、2、3 或 4，还可选择加入不超过 20% 的另一种可共聚单体，共聚物的平均分子量为 5000 至 50000。 将共聚物模塑成颗粒、珠子、薄片、垫子、布或滤芯，用作过滤器，从含有金属离子（如钯、铬或铀离子）的工业废水溶液中吸附除铁或钴以外的金属离子，溶液的 pH 值应调节到适当的水平。共聚物可以用不同 pH 值的水清洗，以回收金属；也可以焚烧，从灰烬中回收金属。