Bis-(n-octylxanthogen)-disulfid | 1851-69-0

• 分子结构分类: 有机化合物 - 有机硫化合物 - 有机二硫化物
• 英文名称: Bis-(n-octylxanthogen)-disulfid
• 英文别名: Dioctylxanthogendisulfid；octylxanthogen disulfide；O-octyl (octoxycarbothioyldisulfanyl)methanethioate
• CAS: 1851-69-0
• 化学式: C₁₈H₃₄O₂S₄
• 分子量: 410.731
• InChiKey: PNRPMUVARHCWEI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  24
• 可旋转键数：
  19
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  133
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Bis-(n-octylxanthogen)-disulfid 在 sulfur 作用下， 生成 Dioctylxanthogentrisulfid
  参考文献：
  名称：

  Synthesis of bisalkylxanthogen trisulfides [O,O-dialkyl trithiobis(thioformates)]

  摘要：

  DOI：

  10.1007/bf00844218
• 作为产物：
  描述：

  sodium octyl xanthate 生成 Bis-(n-octylxanthogen)-disulfid
  参考文献：
  名称：

  ZHOU, CHUNSHAN;BAHR, ALBERT;SCHWEDT, GEORG, FRESENIUS J. ANAL. CHEM., 338,(1990) N, C. 908-911

  摘要：

  DOI：

文献信息

• Comparative study of the13C nuclear magnetic resonance shifts of carbonyl and thiocarbonyl compounds
  作者：Alan R. Katritzky、Stanislaw Sobiak、Charles M. Marson

  DOI：10.1002/mrc.1260260805

  日期：1988.8

  The 13C spectra of nine novel and fifteen known derivatives YC(:X)Z with X = O or S are reported and compared with literature data. Two linear relationships between 13CO and 13CS are established depending on whether or not Y or Z is linked through an O atom to the CX group. General equations for 13CO and 13CS in terms of the attached groups are also deduced. The 13C chemical shifts of n-butyl and n-octyl groups attached to the heteroatoms in this series of compounds are recorded and discussed.

  报道了九种新衍生物和十五种已知衍生物YC(:X)Z（其中X=O或S）的13C谱，并与文献数据进行比较。根据Y或Z是否通过O原子与CX基团相连，建立了两个关于13CO和13CS的线性关系。还推导出关于附着基团的13CO和13CS的一般方程。记录并讨论了这一系列化合物中连接到杂原子的n-丁基和n-辛基的13C化学位移。
• Synthesis and reactivity of molybdenum-sulfur cubes
  作者：C.L. Coyle、K.A. Eriksen、S. Farina、J. Francis、Y. Gea、M.A. Greaney、P.J. Guzi、T.R. Halbert、H.H. Murray、E.I. Stiefel

  DOI：10.1016/s0020-1693(00)92400-9

  日期：1992.8

  A series of tetranuclear Mo4S4(R2NCS2)6 complexes has been prepared by using the 'self-assembly' route as well as by synthesis from well-defined molecular building blocks. A variety of mononuclear, dinuclear and trinuclear building blocks have been successfully used to prepare the tetranuclear Mo4S46+ complexes. These thiocubanes have been prepared with mono-anionic 1,1-dithiolate ligands, which provide each of the Mo atoms with a pseudo-octahedral coordination geometry and result in the formation of neutral species. Mo4S4L6 complexes with dialkyldithiocarbamate (DTC), R2NCS2; dialkyldithiophosphate (DDP), (RO)2PS2; alkylxanthate (XAN), ROCS2; and alkylthioxanthate (THIOXAN), RSCS2 ligands have been prepared. The structure of the Mo4S4(DDP)6 complex was determined by single crystal X-ray structure analysis and is compared with the structures of other known Mo4S4 thiocubane complexes. The synthesis, electrochemistry, reactivity and bonding of the tetranuclear clusters are presented.
• ZHOU, CHUNSHAN;BAHR, ALBERT;SCHWEDT, GEORG, FRESENIUS J. ANAL. CHEM., 338,(1990) N, C. 908-911
  作者：ZHOU, CHUNSHAN、BAHR, ALBERT、SCHWEDT, GEORG

  DOI：——

  日期：——
• Synthesis of bisalkylxanthogen trisulfides [O,O-dialkyl trithiobis(thioformates)]
  作者：K. S. Bokarev、V. A. Kraft、L. M. Kapelyushnikova

  DOI：10.1007/bf00844218

  日期：1964.12