hydroxybutanoic acid hexanoate | 30435-96-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: hydroxybutanoic acid hexanoate
• 英文别名: 4-Hexanoyloxybutanoic acid；4-hexanoyloxybutanoic acid
• CAS: 30435-96-2
• 化学式: C₁₀H₁₈O₄
• 分子量: 202.251
• InChiKey: ZMAWCCRPMJCZNS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-氧代癸酸 在 氧气 、 Baeyer-Villiger monooxygenase from Gordonia sihwensis, mutant C₃₀₈L 、 还原型辅酶II(NADPH)四钠盐 作用下， 以 aq. phosphate buffer 为溶剂， 反应 4.0h， 生成 hydroxybutanoic acid hexanoate
  参考文献：
  名称：

  具有高正常区域选择性的新型 Baeyer-Villiger 单加氧酶的发现和工程化

  摘要：

  结构可控合成：区域选择性在 Baeyer-Villiger 单加氧酶介导的不对称酮的区域发散转化中是必不可少的，以在有机合成中生成酯。鉴定、设计并用于从源自可再生植物油的 10-酮硬脂酸有效合成 9-（壬酰氧基）壬酸的来自Gordonia sihwensis 的新型正常偏好 BVMO，具有优异的区域选择性（97:3）。

  DOI：

  10.1002/cbic.202000478

文献信息

• BIODEGRADABLE COMPOSITION COMPRISING POLYMERS OF NATURAL ORIGIN AND ALIPHATIC-AROMATIC COPOLYESTERS
  申请人：Bastioli Catia

  公开号：US20120316257A1

  公开（公告）日：2012-12-13

  The present invention relates to a biodegradable composition comprising at least one polymer of natural origin and at least one aliphatic-aromatic copolyester obtained starting from mixtures comprising aliphatic diols, polyfunctional aromatic acids, and at least two aliphatic dicarboxylic acids, at least one of which is long chain. Said composition combines improved biodegradability, excellent mechanical properties, a high level of industrial processability, limited environmental impact as well as stability of physical properties under the influence of environmental factors.

  本发明涉及一种可生物降解的组合物，包括至少一种天然来源的聚合物和至少一种由混合物制得的脂肪族芳香共聚酯，该混合物包括脂肪二醇、多官能团芳香酸和至少两种脂肪族二羧酸，其中至少一种是长链的。该组合物具有改善的生物降解性、优异的机械性能、高度的工业可加工性、有限的环境影响以及在环境因素影响下物理性能的稳定性。
• GRADIENT OPTICAL POLYMER NANOCOMPOSITES
  申请人：State of Oregon acting by and through the State Board of Higher Education on behalf of the Univers

  公开号：US20150023643A1

  公开（公告）日：2015-01-22

  Gradient index optical materials are formed by drop by drop dispensing of nanoparticle/monomer suspensions. Refractive index variations are defined by nanoparticle concentrations that can vary in three dimensions. Droplets of differing compositions can be mixed, and droplets or layers or droplets are partially cross-linked by exposure to ultraviolet radiation prior to dispensing additional droplets. Gradient index optical elements such as lenses, prisms, and waveguides can be formed in flexible polymer layers.

  渐变折射率光学材料是通过滴滴分配纳米颗粒/单体悬浮液形成的。折射率变化由纳米颗粒浓度在三个维度上变化定义。不同成分的液滴可以混合，液滴或液滴层可以在分配额外液滴之前通过紫外线辐射部分交联。可以在柔性聚合物层中形成渐变折射率光学元件，如透镜、棱镜和波导。
• Sustained release pharmaceutical compositions for the parenteral administration of hydrophilic compounds
  申请人：——

  公开号：US20030171299A1

  公开（公告）日：2003-09-11

  Stable, biologically compatible pharmaceutical compositions in the form of water-in-oil microemulsions (w/o), for the sustained release by parenteral administration of active ingredients which are hydrophilic or are made hydrophilic by suitable derivatization, a process for the preparation of said microemulsions and the use thereof.

  稳定、生物相容性的制药组合物以水/油微乳液（w/o）的形式存在，用于通过肌肉注射进行持续释放亲水性活性成分或通过适当衍生化使其亲水性，本发明涉及制备上述微乳液的方法和使用方法。
• METHOD FOR CULTURING MICROORGANISM, AND PROCESS FOR PRODUCING SUBSTANCE WITH MICROORGANISM
  申请人：Kaneka Corporation

  公开号：EP2418277A1

  公开（公告）日：2012-02-15

  Using as a carbon source a long chain fatty acid which has not necessarily been efficaciously used in industry, culture of a microorganism and production of a substance by the microorganism are industrially efficiently carried out. A microorganism is cultured in the presence of a carbon source including any one of the following compositions: (1) a fatty acid composition containing at least two fatty acids selected from the group consisting of lauric acid, myristic acid, palmitic acid and oleic acid; and (2) a mixed composition containing at least one fatty acid selected from the group consisting of lauric acid, myristic acid, palmitic acid and oleic acid, and a fat and oil, and having a content of the fatty acid of not less than 10% by weight.

  使用不一定在工业中有效使用的长链脂肪酸作为碳源，可在工业中有效地培养微生物并通过微生物生产物质。在碳源存在的情况下培养微生物，碳源包括以下任何一种组合物：(1) 脂肪酸组合物，其中含有至少两种选自月桂酸、肉豆蔻酸、棕榈酸和油酸的脂肪酸；(2) 混合组合物，其中含有至少一种选自月桂酸、肉豆蔻酸、棕榈酸和油酸的脂肪酸，以及脂肪和油，且脂肪酸含量不低于 10%（重量百分比）。
• BIODEGRADABLE CONTAINER, METHOD FOR OBTAINING SAME AND USE THEREOF FOR CONTACT, TRANSPORT AND/OR STORAGE OF PERISHABLE PRODUCTS
  申请人：Nastepur, S.L.

  公开号：EP3907078A1

  公开（公告）日：2021-11-10

  The present invention relates to a biodegradable container comprising a thermoformable structural layer with tear resistance and low cost, and optionally an adhesive barrier layer, an adhesive active layer and/or a layer in direct contact with the product, all of which are based on biodegradable polymers. Furthermore, the present invention relates to the method for obtaining same and to use thereof for contact, transport and/or storage of perishable products.

  本发明涉及一种可生物降解容器，该容器包括一个具有抗撕裂性和低成本的热成型结构层，以及可选的粘合阻隔层、粘合活性层和/或与产品直接接触的层，所有这些层都基于可生物降解聚合物。此外，本发明还涉及获得上述材料的方法，以及将其用于易腐产品的接触、运输和/或储存。