trihexyl(tetradecyl)ammonium bis(trifluoromethane)sulfonimide | 950183-42-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磺酸及其衍生物
• 英文名称: trihexyl(tetradecyl)ammonium bis(trifluoromethane)sulfonimide
• 英文别名: tri(hexyl)tetradecylammonium bis(trifluoromethyl)sulfonylimide；[H3TDA][TFSI]；Bis(trifluoromethylsulfonyl)azanide;trihexyl(tetradecyl)azanium；bis(trifluoromethylsulfonyl)azanide;trihexyl(tetradecyl)azanium
• CAS: 950183-42-3
• 化学式: C₂F₆NO₄S₂*C₃₂H₆₈N
• 分子量: 747.047
• InChiKey: TZQQAKLBFXIBCV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.3
• 重原子数：
  48
• 可旋转键数：
  30
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  86
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  十四烷基三己基溴化铵 、 bis(trifluoromethane)sulfonimide lithium 以 氯仿 、 水 为溶剂， 反应 16.0h， 以96%的产率得到trihexyl(tetradecyl)ammonium bis(trifluoromethane)sulfonimide
  参考文献：
  名称：

  Tuning cation–anion interactions in ionic liquids by changing the conformational flexibility of the cation

  摘要：

  XPS实验表明，通过在季铵阳离子的取代链中引入构象限制，阴离子-阳离子基于相互作用可能得到增强。

  DOI：

  10.1039/c4cc05505e

文献信息

• Opto-electronic devices exhibiting enhanced efficiency
  申请人：Liu Jie

  公开号：US20070215879A1

  公开（公告）日：2007-09-20

  Described herein is an organic opto-electronic device comprising a cathode comprising at least one zero-valent metal; an anode; an opto-electronically active organic material; wherein said cathode is in contact with at least one organic ammonium salt. In certain embodiments, the organic ammonium salt has structure (I) wherein R 1 -R 4 are independently at each occurrence a C 1 -C 20 aliphatic radical, a C 3 -C 20 cycloaliphatic radical, or a C 3 -C 20 aromatic radical is disclosed and wherein X + is selected from the group consisting of monovalent inorganic anions, monovalent organic anions, polyvalent inorganic anions, polyvalent organic anions, and mixtures thereof.
• Tuning cation–anion interactions in ionic liquids by changing the conformational flexibility of the cation
  作者：R. K. Blundell、P. Licence

  DOI：10.1039/c4cc05505e

  日期：——

  XPS experiments reveal that anion–cation based interactions may be enhanced by the introduction of conformational restriction into substituent chains of quaternary ammonium cations.

  XPS实验表明，通过在季铵阳离子的取代链中引入构象限制，阴离子-阳离子基于相互作用可能得到增强。