2,2-diphenyl-1,3-dioxa-2-stannolane | 53723-70-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-diphenyl-1,3-dioxa-2-stannolane
• 英文别名: 2,2-Diphenyl-1,3,2-dioxastannolane
• CAS: 53723-70-9
• 化学式: C₁₄H₁₄O₂Sn
• 分子量: 332.974
• InChiKey: ZVRRNSMZXDUOOG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.29
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  乙二醇 、 dibutyltin(IV) oxide 以 环己烷 为溶剂， 以97%的产率得到2,2-diphenyl-1,3-dioxa-2-stannolane
  参考文献：
  名称：

  Une méthode simple et efficace de préparation des dihydrures organotanniques

  摘要：

  A new and efficient method of preparation of R(2)SnH(2) is proposed. Organodioxastannolanes were used as starting materials, these compounds being easily obtained by azeotropic distillation of water from a solution of diorganotin oxides and 1,2 diols in cyclohexane. Their reduction by commercial BH3/THF complex gave raw dialkyltin dihydrides with excellent yields and high purity degrees.

  DOI：

  10.1016/0022-328x(94)05356-g

文献信息

• Une méthode simple et efficace de préparation des dihydrures organotanniques
  作者：H. Deleuze、B. Maillard

  DOI：10.1016/0022-328x(94)05356-g

  日期：1995.3

  A new and efficient method of preparation of R(2)SnH(2) is proposed. Organodioxastannolanes were used as starting materials, these compounds being easily obtained by azeotropic distillation of water from a solution of diorganotin oxides and 1,2 diols in cyclohexane. Their reduction by commercial BH3/THF complex gave raw dialkyltin dihydrides with excellent yields and high purity degrees.