benzoyl chloride <2,4,6-d3> | 110375-01-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzoyl chloride <2,4,6-d3>
• 英文别名: (2.4.6-D3)-Benzoylchlorid；2,4,6-trideuterio-benzoyl chloride
• CAS: 110375-01-4
• 化学式: C₇H₅ClO
• 分子量: 143.545
• InChiKey: PASDCCFISLVPSO-NHPOFCFZSA-N

反应信息

• 作为反应物：
  描述：

  benzoyl chloride <2,4,6-d3> 在 potassium hydrosulfide 作用下， 以85%的产率得到thiolbenzoic acid <2,4,6-d3>
  参考文献：
  名称：

  Comparison of the fragmentations and reactivities of positive and negative ions. Thiocarboxylate ions

  摘要：

  Abstract(1) Thiocarboxylate anions [RCOS]− formed by dissociative secondary electron capture are either stable or fragment to yield [R]−. (2) Thiocarboxylate cations [RCOS]+ formed by charge stripping from [RCOS]−, fragment to form [R]+, [COS]+. and [RCO]+ (not when R=CF3). (3) Aryl hydrogen scrambling is observed in the case of the thiobenzoate cation. Aliphatic hydrogen scrambling is not detected for the thiopropionate cation.

  DOI：

  10.1002/oms.1210161007