| 133410-05-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 133410-05-6
• 化学式: C₂₄H₃₁P
• 分子量: 350.484
• InChiKey: SMTGNQOZAJXSEX-HOCLYGCPSA-N

反应信息

• 作为反应物：
  描述：

  carbon monoxide;cyclohepta-1,3,5-triene;molybdenum 、 以 正己烷 为溶剂， 以60%的产率得到
  参考文献：
  名称：

  Preparation and reactivity of PhP(C5Me4H)2 and Ph2P(C5Me4H). X-ray crystal structures of Mo(CO)5[Ph2P(C5Me4H)] and (η5-C5Me4H)Mo(CO)(μ-PPh2)2Mo[(η5-C5Me4)P(O)Ph2](CO) · 1/4C6H14

  摘要：

  The phosphine ligands PhP(C5Me4H)2, I, and Ph2P(C5Me4H), II, can be prepared via the interaction of PhPCl2 and Ph2PCl with two and one equivalents(s) of (C5Me4H)Li, respectively. At ambient temperature, C7H8Mo(CO)4 reacts with I-II to give the corresponding Mo(CO)5L complex, III-IV ]III, L = PhP(C5M34H)2; IV, L = PH2P(C5Me4H)[, in moderate yield (60-65%). In refluxing hexane, C7H8Mo(CO)4 reacts with II to give (eta-5-C 5Me4H)Mo(CO)(mu-PPh2)2Mo](eta-5-C5Me4)P(O)Ph2[(CO) 1/4C6H14, V, in low yield (10%). Structures of IV and V have been determined by X-ray crystallography.

  DOI：

  10.1016/s0277-5387(00)84199-6