chloro(maltolato)benzoyldiazenidobis(triphenylphosphine)rhenium(III) | 137954-60-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: chloro(maltolato)benzoyldiazenidobis(triphenylphosphine)rhenium(III)
• CAS: 137954-60-0
• 化学式: C₄₉H₄₀ClN₂O₄P₂Re
• 分子量: 1004.48
• InChiKey: NALACXVVXSATHD-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  麦芽醇 、 rhenum(V) dichloro-η2-benzoylhydrazido(3-) bis(triphenylphosphine) 在 triethylamine 作用下， 以 乙醇 为溶剂， 生成 chloro(maltolato)benzoyldiazenidobis(triphenylphosphine)rhenium(III)
  参考文献：
  名称：

  The preparation and characterization of some imido- and diazenido-rhenium complexes of maltol. The X-ray crystal structure of [Re(maltol)2(NPh)(PPh3)][BPh4]

  摘要：

  The imido complex [ReCl3(NPh)(PPh3)2] reacts with excess maltol to give the green complex [Re(maltol)2(NPh)(PPh3)][BPh4] (1). Under analogous conditions, [ReCl2(N2COPh)(PPh3)2] gives [ReCl(maltol)(N2COPh)(PPh3)2] (2). An X-ray crystal structure of complex 1 revealed a distorted octahedral structure with cis-maltol ligands. Preliminary X-ray data on a poorly diffracting crystal of complex 2 has confirmed the formulation and stereochemistry. The possible structures of products from other precursors are discussed together with their redox and spectroscopic properties.

  DOI：

  10.1016/s0277-5387(00)86077-5