PtH(P(CH2CH2PPh2)3-P,P',P'',P''')(1+) | 109783-01-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: PtH(P(CH2CH2PPh2)3-P,P',P'',P''')(1+)
• CAS: 109783-01-9
• 化学式: C₄₂H₄₃P₄Pt
• 分子量: 866.778
• InChiKey: UCNSLVQDBKVLJL-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  PtH(P(CH2CH2PPh2)3-P,P',P'',P''')(1+) 在 sodium amalgam 作用下， 以 not given 为溶剂， 生成 Pt2(μ-(P(CH2CH2PPh2)3)2)
  参考文献：
  名称：

  Synthesis of the five-coordinate organoplatinum cation [PtMe(pp3)]+ (pp3 =P(CH2CH2PPh2)3) by oxidative addition of methyl iodide to [Pt2(μ-pp3)2]

  摘要：

  The complex [Pt2(mu-pp3)2] (pp3 =P(CH2CH2PPh2)3), produced by treatment of [PtH(pp3)]+ with sodium amalgam, has been shown to react with methyl iodide to give [PtMe(pp3)]+. The new complexes have been characterized by H-1, P-31 and Pt-195 NMR spectroscopy.

  DOI：

  10.1016/0022-328x(91)80015-c
• 作为产物：
  描述：

  Pt2(μ-(P(CH2CH2PPh2)3)2) 在 乙醇 、 水 作用下， 以 乙醇 、 水 为溶剂， 生成 PtH(P(CH2CH2PPh2)3-P,P',P'',P''')(1+)
  参考文献：
  名称：

  Synthesis of the five-coordinate organoplatinum cation [PtMe(pp3)]+ (pp3 =P(CH2CH2PPh2)3) by oxidative addition of methyl iodide to [Pt2(μ-pp3)2]

  摘要：

  The complex [Pt2(mu-pp3)2] (pp3 =P(CH2CH2PPh2)3), produced by treatment of [PtH(pp3)]+ with sodium amalgam, has been shown to react with methyl iodide to give [PtMe(pp3)]+. The new complexes have been characterized by H-1, P-31 and Pt-195 NMR spectroscopy.

  DOI：

  10.1016/0022-328x(91)80015-c