bis[1-(2-bromo-4-methylphenyliminomethyl)-2-naphtholato-N,O]copper(II) | 211861-57-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: bis[1-(2-bromo-4-methylphenyliminomethyl)-2-naphtholato-N,O]copper(II)
• 英文别名: bis[N-(2-bromo-4-methylphenyl)naphthaldiminato]copper(II)
• CAS: 211861-57-3
• 化学式: C₃₆H₂₆Br₂CuN₂O₂
• 分子量: 741.969
• InChiKey: PDOLQOSIBUKAOZ-BAHFGYRZSA-L

反应信息

• 作为产物：
  描述：

  2-溴-4-甲基苯胺 、 2-羟基-1-萘甲醛 、 copper(II) acetate monohydrate 以 甲醇 、 乙腈 为溶剂， 生成 bis[1-(2-bromo-4-methylphenyliminomethyl)-2-naphtholato-N,O]copper(II)
  参考文献：
  名称：

  Bis[N-(2-bromo-4-methylphenyl)naphthaldiminato]copper(II)

  摘要：

  The title compound, bis[1-(2-bromo-4-methylphenyl-iminomethyl)-2-naphtholato-N,O]copper(II), [Cu(C18H13-BrNO)(2)], has crystallographic inversion symmetry. The Cu-II ion shows a pseudo-square-planar coordination. The Cu-N and Cu-O distances are 1.990(4) and 1.880 (4) Angstrom, respectively. The Cu-II ion is in an approximate octahedral environment if bromine is included in the description, with a non-bonded Cu ... Br distance of 3.296 (1) Angstrom.

  DOI：

  10.1107/s0108270198003345