Resonance Raman Spectroelectrochemical Study of (.mu.-3,3',4,4'-Tetraimino-3,3',4,4'-tetrahydrobiphenyl)bis[bis(bipyridine)ruthenium(II)](4+) and Its One-, Two-, and Four-Electron-Reduction Products
摘要:
We report resonance Raman data over a range of excitation wavelengths for the title complex and its one-, two-, and four-electron-reduced products. Assignments previously reported are generally supported by these observations. The nature of the various excited states is discussed on the basis of the enhanced, coupled vibrations.