[Ru(Me2PCH2CH2PMe2)2Me][(3,5-(CF3)2C6H3)4B] | 239078-77-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ru(Me2PCH2CH2PMe2)2Me][(3,5-(CF3)2C6H3)4B]
• CAS: 239078-77-4
• 化学式: C₁₃H₃₅P₄Ru*C₃₂H₁₂BF₂₄
• 分子量: 1279.61
• InChiKey: WWEMWBDQTMCMII-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  tetrakis[3,5-bis(trifluoromethyl)phenyl]boric acid bis(diethyl ether) complex 、 cis-[Ru(Me2PCH2CH2PMe2)2(Me)2] 以 二氯甲烷-D2 为溶剂， 生成 [Ru(Me2PCH2CH2PMe2)2Me][(3,5-(CF3)2C6H3)4B]
  参考文献：
  名称：

  Synthesis and single-crystal X-ray structure of [(DMPE)2Ru(C2H4)CH3]+[(3,5-(CF3)2C6H3)4B]−

  摘要：

  The reaction of cis-(DMPE)(2)Ru(CH3)(2) with [(3,5-(CF3)(2)C6H3)(4)B](-)[H(OEt2)(2)](+) afforded the ruthenium cation [(DMPE)(2)RuCH3](+) [(3,5-(CF3)(2)C6H3)(4)B](-). This cation underwent reaction with ethylene at room temperature to give the stable adduct trans-[(DMPE)(2)Ru(C2H4)CH3](+) [(3,5-(CF3)(2)C6H3)(4)B](-), 1. The single crystal X-ray structure of 1 is reported. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)01212-1