| 400625-53-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 400625-53-8
• 化学式: C₅₀H₅₈MnN₆
• 分子量: 797.989
• InChiKey: XILCBKRFRQQCPR-USYMPASTSA-N

反应信息

• 作为反应物：
  描述：

  [fac-Re(CO)3Cl(Zn(2,8,12,18-tetrabutyl-3,7,13,15-tetramethyl-5,15-bis(4-pyridyl)porphinate))]4 、 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Artificial Enzymes Formed through Directed Assembly of Molecular Square Encapsulated Epoxidation Catalysts

  摘要：

  Supramolecular complex formation imparts stability and substrate selectivity to a simple manganese-porphyrin-based epoxidation catalyst. Lewis acid/Lewis base directed assembly was used to encapsulate the epoxidation catalyst within a supramolecular square structure to form an enzyme-like catalyst system. The "molecular square" takes on the functions of the protein superstructure in an enzyme: it spatially protects the catalytic core from decomposition and induces reaction selectivity.

  DOI：

  10.1002/1521-3773(20011119)40:22<4239::aid-anie4239>3.0.co;2-e