This study investigates the gate-opening closed-to-open-pore structural transition of a porouscoordinationpolymer induced by CO2 adsorption. Solid-state 13C NMR examination of adsorbed CO2 and framework dynamics reveals the surface adsorption state of the closed structure below the transition pressure and an intermediate structure during the transition process.
本研究研究了CO 2吸附诱导的多孔配位聚合物的开门闭孔到开孔结构转变。吸附CO 2和骨架动力学的固态13 C NMR检查揭示了低于转变压力的封闭结构的表面吸附状态以及转变过程中的中间结构。