trans-bis(dimethylglyoximato-κ2N,N')(1-hexenyl)(pyridine-κN)cobalt(III) | 581093-89-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: trans-bis(dimethylglyoximato-κ2N,N')(1-hexenyl)(pyridine-κN)cobalt(III)
• CAS: 581093-89-2
• 化学式: C₁₉H₃₀CoN₅O₄
• 分子量: 451.471
• InChiKey: FBGCNRNPSGUHCE-NMBSQECASA-L

反应信息

• 作为反应物：
  描述：

  trans-bis(dimethylglyoximato-κ2N,N')(1-hexenyl)(pyridine-κN)cobalt(III) 以 氘代氯仿 为溶剂， 生成 trans-bis(dimethylglyoximato-κ2N,N')((E)-2-hexenyl)(pyridine-κN)cobalt(III)
  参考文献：
  名称：

  trans-Bis(dimethylglyoximato-κ²N,N′)(1-hexenyl)(pyridine-κN)cobalt(III): a cobaloxime-substituted terminal alkene that rapidly isomerizes to a cobaloxime-substituted internal alkenyl complex

  摘要：

  An unusual cobaloxime-substituted terminal alkene, [Co(C6H11)(C4H7N2O2)(2)(C5H5N)], has been isolated and characterized by X-ray crystallography. The double bond in the alkene readily isomerizes, but the title compound could be isolated and structurally characterized at low temperature.

  DOI：

  10.1107/s0108270103006899