N'-(4'-benzo[15-crown-5])phenylaminoglyoxime | 679786-10-8

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: N'-(4'-benzo[15-crown-5])phenylaminoglyoxime
• CAS: 679786-10-8
• 化学式: C₂₂H₂₇N₃O₇
• 分子量: 445.472
• InChiKey: OWAUIBKKBUEGDN-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  copper(II) choride dihydrate 、 N'-(4'-benzo[15-crown-5])phenylaminoglyoxime 在 sodium hydroxide 作用下， 以 乙醇 为溶剂， 以83%的产率得到
  参考文献：
  名称：

  Synthesis of N′‐(4′‐Benzo[15‐crown‐5]‐phenylaminoglyoxime and Its Complexes with Copper(II), Nickel(II), and Cobalt(II)

  摘要：

  N'-(4'-Benzo[15-crown-5]phenylaminoglyoxime (H2L) and the sodium chloride adduct of N'-(4'-benzo[15-crown-5]phenylaminoglyoxime ((H2LNaCl)-Na-.) have been prepared from chlorophenylglyoxime, 4'-aminobenzo[15-crown-5] and sodium bicarbonate or sodium bicarbonate and sodium chloride. Nickel(II), cobalt(II) and copper(II) complexes of H2L and H2L-NaCl have a metal-ligand ratio of 1:2 and the ligand coordinates through the two N atoms, as do most of the vic-dioximes. Their IR spectra and elemental analyses are given, together with H-1 NMR spectra of the ligands.

  DOI：

  10.1081/sim-120024312