Phoban[4.2.1]-C3NMe | 132944-15-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Phoban[4.2.1]-C3NMe
• 英文别名: 9-(C3H6NMe2)-9-phosphabicyclo[4.2.1]nonane
• CAS: 132944-15-1
• 化学式: C₁₃H₂₆NP
• 分子量: 227.33
• InChiKey: BOPUREXYKQNBEW-NNQSOWQGSA-N

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 Phoban[3.3.1]((CH2)3NMe2) 、 Phoban[4.2.1]-C3NMe 以 二氯甲烷 为溶剂， 生成 cis-[dichlorido(Phoban[3.3.1]-C3NMe2)(Phoban[4.2.1]-C3NMe2)platinum(II)] 、 cis-dichloridobis[dimethyl[3-(9-phosphabicyclo[3.3.1]non-9-yl)propyl]amine-κP]platinum(II) 、 cis-dichloridobis[dimethyl[3-(9-phosphabicyclo[4.2.1]non-9-yl)propyl]amine-κP]platinum(II)
  参考文献：
  名称：

  cis-Dichloridobis{dimethyl[3-(9-phosphabicyclo[3.3.1]non-9-yl)propyl]amine-κP}platinum(II)

  摘要：

  The title compound, [PtCl2(C13H26NP)(2)], is a rare example of a sterically bulky ligand adopting a cis geometry in a square-planar complex. It crystallizes on a twofold rotation axis which bisects the Pt centre and the P-Pt-P' and Cl-Pt-Cl' angles. The ligand exhibits a random packing disorder in the N,N-dimethylpropylamine substituent, with the two orientations refining to occupancies of 0.404(15) and 0.596 (15). Weak intermolecular interactions between a Cl and a H atom of the ligand of a neighbouring molecule result in extended chains along the a axis. The effective cone angle for the dimethyl[3-(9-phosphabicyclo[3.3.1]non-9-yl)propyl]amine (Phoban[3.3.1]-C3NMe2)ligand was determined as being in the range 160-181 degrees, depending on the choice of atoms used in the calculations.

  DOI：

  10.1107/s0108270109005162