[Cu(I)(2,9-dimethyl-1,10-phenanthroline)2][Cu(II)(hexafluoroacetylacetonate)3] | 680204-19-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(I)(2,9-dimethyl-1,10-phenanthroline)2][Cu(II)(hexafluoroacetylacetonate)3]
• CAS: 680204-19-7
• 化学式: C₁₅H₃CuF₁₈O₆*C₂₈H₂₄CuN₄
• 分子量: 1164.77
• InChiKey: KFNUAKFYYYFADR-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  新铜试剂 、 (1,5-cyclooctadiene)copper(I) hexafluoroacetylacetonate 以 乙腈 为溶剂， 生成 [Cu(I)(2,9-dimethyl-1,10-phenanthroline)2][Cu(II)(hexafluoroacetylacetonate)3]
  参考文献：
  名称：

  A novel type of copper(I)/(II) mixed-valence compound: [CuI(dmp)2]+[CuII(hfac)3]− with dmp=2,9-dimethyl-1,10-phenanthroline and hfac−=hexafluoroacetylacetonate

  摘要：

  The mixed-valence compound [Cu-I(dmp)(2)][Cu-II(hfac)(3)] with dmp = 2,9-dimethyl-1,10-phenanthroline and hfac(-) = hexafluoroacetylacetonate has been synthesized and structurally characterized by X-ray crystallography. The MV interaction has been examined by emission spectroscopy. The phosphorescence of [Cu-I(dmp)(2)](+) is completely quenched. It is suggested that this quenching takes place by excited state electron transfer from Cu(I) to Cu(II). (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.07.007