azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-κ3P,N1,O]nickel(II) | 1188591-58-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-κ3P,N1,O]nickel(II)
• CAS: 1188591-58-3
• 化学式: C₂₀H₁₇N₆NiOP
• 分子量: 447.058
• InChiKey: DOJRQMIZJGOYEJ-IFGMWRHRSA-M

反应信息

• 作为产物：
  描述：

  sodium azide 、 nickel(II) nitrate hexahydrate 、 2-(diphenylphosphino)benzaldehyde semicarbazone 以 乙醇 为溶剂， 生成 azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-κ3P,N1,O]nickel(II)
  参考文献：
  名称：

  Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-κ²P,N¹,O]nickel(II)

  摘要：

  The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.

  DOI：

  10.1107/s0108270109021970