diethyl (E)-N-(3,4-dichlorophenylcarbamoyloxy)-3-fluorobenzimidoylphosphonate | 1206515-57-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diethyl (E)-N-(3,4-dichlorophenylcarbamoyloxy)-3-fluorobenzimidoylphosphonate
• CAS: 1206515-57-2
• 化学式: C₁₈H₁₈Cl₂FN₂O₅P
• 分子量: 463.229
• InChiKey: UXOJRUQZPYGHBJ-HAVVHWLPSA-N

反应信息

• 作为产物：
  描述：

  diethyl N-hydroxy-3-fluorobenzimidoylphosphonate 、 3,4-二氯苯异氰酸酯 反应 6.0h， 生成 diethyl (Z)-N-(3,4-dichlorophenylcarbamoyloxy)-3-fluorobenzimidoylphosphonate 、 diethyl (E)-N-(3,4-dichlorophenylcarbamoyloxy)-3-fluorobenzimidoylphosphonate
  参考文献：
  名称：

  α-Hydroxy- and (α-acyloxyimino)benzylphosphonates

  摘要：

  N-Hydroxyfluorobenzimidoylphosphonates and their O-acyl derivatives are synthesized. Reaction of phosphorylated oximes with sulfinyl chloride proceeds with rearrangement and leads to synthetically prospective N-sulfonylimidoylphosphonates. By the method of F-19 NMR are revealed values of sigma-constants of N-hydroxy- and N-acyloxy substituted imidoylphosphonate groups.

  DOI：

  10.1134/s1070363209020054