4,4'-di[(3-methyl-6-tert-butyl-catecholato)triphenylantimony(V)] | 849642-25-7

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 4,4'-di[(3-methyl-6-tert-butyl-catecholato)triphenylantimony(V)]
• CAS: 849642-25-7
• 化学式: C₅₈H₅₆O₄Sb₂
• 分子量: 1060.58
• InChiKey: ZEESCDWSSJASKW-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  [4-(2-methyl-5-tert-butyl-cyclohexadiene-1,5-dion-3,4-yl)-3-methyl-6-tert-butyl-catecholato] triphenylantimony(V) 以 甲苯 为溶剂， 生成 4,4'-di[(3-methyl-6-tert-butyl-catecholato)triphenylantimony(V)]
  参考文献：
  名称：

  Features of photolytic transformation of [4-(2-methyl-5-t-butyl-cyclohexadiene-1,5-dion-3,4-yl)-3-methyl-6-tert-butyl-catecholato]triphenylantimony(V)

  摘要：

  Photolysis of [4-(2-methyl-5-tert-butyl-cyclohexadiene-1,5-dion-3,4-yl)-3-methyl-6-t-butyl-catecholato]triphenylantimony(V) in toluene by irradiation with the light of wavelength 546 nm leads to excitation of the molecule of parent compound which reacts with a molecule of Ph(3)SbCatQ affording 4,4'-di-(3-methyl-6-tert-butyl-o-benzoquinone) and 4,4'-di[(3-methyl-6-tert-butyl-catecholato)triphenylantimony(V)]. The formed compounds react with each other returning the system into the initial state. Action of light of wavelength 3 13 and 405 nm on the initial reaction mixture leads to the formation of carbon monoxide, Ph(3)SbCatCatSbPh(3) and the products of photolytic transformation of 4,4'-di(3-methyl-6-tert-butyl-o-benzoquinone).

  DOI：

  10.1134/s1070363209070123