(2,3,7,8,12,13,17,18-octaethylcorrolato)cobalt | 66021-56-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (2,3,7,8,12,13,17,18-octaethylcorrolato)cobalt
• 英文别名: (2,3,7,8,12,13,17,18-octaethylcorrolato)cobalt(III)；cobalt(III) octaethylcorrole
• CAS: 66021-56-5
• 化学式: C₃₅H₄₃CoN₄
• 分子量: 578.746
• InChiKey: AFBRQYXFJSIDCA-PWSAZOBDSA-N

反应信息

• 作为反应物：
  描述：

  (2,3,7,8,12,13,17,18-octaethylcorrolato)cobalt 、 苯基溴化镁 在 air 作用下， 以 乙醚 、 二氯甲烷 为溶剂， 以73%的产率得到(σ-phenyl)(2,3,7,8,12,13,17,18-octaethylcorrole)cobalt(IV)
  参考文献：
  名称：

  Will, Stefan; Lex, Johann; Vogel, Emanuel, Inorganic Chemistry, 1996, vol. 35, # 19, p. 5577 - 5583

  摘要：

  DOI：
• 作为产物：
  描述：

  (σ-phenyl)(2,3,7,8,12,13,17,18-octaethylcorrole)cobalt(IV) 以 not given 为溶剂， 生成 (2,3,7,8,12,13,17,18-octaethylcorrolato)cobalt
  参考文献：
  名称：

  Will, Stefan; Lex, Johann; Vogel, Emanuel, Inorganic Chemistry, 1996, vol. 35, # 19, p. 5577 - 5583

  摘要：

  DOI：

文献信息

• Thermal Isomerization of N-Bridged Cobalt Corrole Complexes through a Transiently Formed Axial Carbenoid
  作者：Prosenjit Chattopadhyay、Takashi Matsuo、Takanori Tsuji、Jun Ohbayashi、Takashi Hayashi

  DOI：10.1021/om101113x

  日期：2011.4.11

  The reaction of cobalt(III) octaethylcorrole (CoOEC) with ethyl diazoacetate (EDA) under a nitrogen atmosphere led to the formation of bridged complexes with the carbene moiety inserted into one of the cobalt-nitrogen bonds. The bridged complexes underwent unique thermal isomerization, presumably via the transiently formed axial carbene complex. One of the thermodynamic isomers was characterized by H-1 NMR and mass spectroscopic methods.