diiodobis(2-aminopyridine)cadmium(II) | 84577-90-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: diiodobis(2-aminopyridine)cadmium(II)
• 英文别名: [Cd(2-aminopyridine)₂I₂]；[Cd(2ap)₂I₂]
• CAS: 84577-90-2
• 化学式: C₁₀H₁₂CdI₂N₄
• 分子量: 554.451
• InChiKey: UDPKSAXAZLSXGD-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 cadmium(II) iodide 以 甲醇 为溶剂， 反应 3.0h， 生成 diiodobis(2-aminopyridine)cadmium(II)
  参考文献：
  名称：

  Synthesis, growth, spectral, X-ray diffraction, magnetic and thermal studies of metal–organic complex: Diiodobis(2-aminopyridine)Cadmium(II) single crystal

  摘要：

  The metal-organic hybrid complex, [Cd(2ap)(2)I-2] (DIAC), (2ap = 2-aminopyridine) was synthesized, DIAC single crystal has been grown and characterized by FT-IR, FT-Raman, FT-H-1 NMR, single crystal X-ray diffraction, high resolution X-ray diffraction (HRXRD), UV-Vis-NIR transmission, magnetic and thermal studies. The metal-ligand formation of the title complex was analyzed by FT-IR, FT-Raman and H-1 NMR spectroscopic studies. The DIAC crystallizes in monoclinic crystal system, space group P2(1)/n. The coordination geometry around the Cd(II) center is a distorted tetrahedral. The single-crystal structure analysis showed that DIAC displayed three-dimensional structures containing inorganic-organic motifs with two-dimensional layers pillar-connected through hydrogen bonding framework. The high resolution X-ray diffraction studies (HRXRD) reveals that the crystalline perfection of as grown single crystal is fairly good. Thermal stability of title compound was studied by TG/DTA analysis. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2013.03.039